화학공학소재연구정보센터
Electrochimica Acta, Vol.214, 156-164, 2016
3D Porous Carbon Encapsulated SnO2 Nanocomposite for Ultrastable Sodium Ion Batteries
3D porous carbon encapsulated SnO2 nanoparticles composite (SnO2-PC) prepared by an efficient in situ methodology was applied as anode for sodium ion batteries (SIBS). It delivered a high reversible specific capacity of 280.1 mAhg(-1) after 250 cycles at a current density of 100 mAg(-1), with ultrahigh capacity retention of 91.63%. Notably, it can Exhibit 100 mAh g(-1) after 1000 cycles even at a high current density of 1600 mAg(-1). These greatly enhanced electrochemical properties of SnO2-PC composite can be attributed to the superior structure that the electrical conductivity of the composite was improved by the porous carbon matrix, moreover, it can serve as a cushion during the process of Na ion insertion/extraction into the composite. Significantly, this kind of in situ synthesis method is portable for other similar composite. (C) 2016 Elsevier Ltd. All rights reserved.