Melt Intercalation방법에 의한 Poly(ethylene oxide)/몬모릴로나이트 나노복합재료 제조

최현국; 박영해; 유성구; 김봉식; 서길수; H. K. Choi; Y. H. Park; S. G. Lyu; B. S. Kim; G. S. Sur

Polymer(Korea), Vol.23, No.3, 456-462, May, 1999

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Melt Intercalation방법에 의한 Poly(ethylene oxide)/몬모릴로나이트 나노복합재료 제조

The Preparation of Poly(ethylene oxide)/Montmorillonite Nanocomposites through Melt Intercalation

최현국, 박영해¹, 유성구 ², 김봉식 ², 서길수 ^{2, †}

상주대학교 화학공학과
¹영남이공대학 화학공학과
²영남대학교 공과대학 화공학부 및 고분자 소재 연구 센터

H. K. Choi, Y. H. Park¹, S. G. Lyu², B. S. Kim², and G. S. Sur^{2, †}

Department of Chemical Engineering, Sungju National Unviersity, Sangju 742-711, Korea
¹Department of Chem. Indus., Yeungnam College of Science & Technology, Taegu 705-037, Korea
²School of Chemical Engineering & Research Center for Polymer Materials, Yeungnam University, Gyungsan 712-749, Korea

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초록

Polyethylene oxide (PEO)를 용융삽입법 (melt intercalation)으로 sodium montmorillote (Na⁺+ -MMT에 삽입된 P대의 배열형태는 나선형 형태임을 확인하였으며, XRD와 투과전자현미경 (TEM)으로 연구한 결과 실리케이트는 10-13겹으로 뭉쳐서 PEO의 매트릭스에 분산되어 있음을 확인하였다.

We have studied the melt intercalation of polyethylene oxide (PEO) into sodium montrmorillonite (Na(+)-MMT), a layered silicate. X-ray diffraction (XRD) experiments on polymer/silicate composite samples demonstrated that the intercalation of polymer chains lead to increase in the spacing between silicate layers. But the molecular weight and amounts of PEO have no effect on the d-spacing values between silicate layers. As the intercalation reaction proceed, in the study of differential scanning calorimetry (DSC), MORE PEO chains were intercalated and area of the endotherm correspondign to the crystalline PEO was reduced. In this study, the PEO chaing conformations which were intercalated into Na(+)-MMT were the helical structures. From the study of XRD and transmission electron microscopy (TEM), we found that the 10-13 multilayer silicates were dispersed in PEO matrix.

Keywords:sodium montmorillonite;polyethylene oxide;intercalation;composite;nanocomposite

[References]

Ryu JG, Park GR, Lyu SG, Rhew JH, Sur GS, Polym.(Korea), 22(2), 328 (1998)
Lan T, Pinnavaia T, Chem. Mater., 6, 2216 (1994)
Kaviratna PD, Lan T, Pinnavaia T, Polym. Prepr., 35, 788 (1994)
Wang MS, Pinnavaia T, Chem. Mater., 6, 468 (1994)
Kojima Y, Usuki A, Okada A, Kawasumi M, Okada A, Kurauchi T, Kumigaito O, J. Polym. Sci. A: Polym. Chem., 31, 983 (1993)
Messersmith PB, Giannelis EP, J. Polym. Sci. A: Polym. Chem., 33(7), 1047 (1995)
Yano K, Usuki A, Kurauchi T, Kamigaito OJ, J. Polym. Sci. A: Polym. Chem., 31, 2493 (1993)
Sur GS, Ryu JG, Lyu SG, Polym. Abstract(Korea), 22(2), 139 (1997)
Ryu JG, Park GR, Sur GS, Polym. Abstract(Korea), 23(1), 180 (1998)
Ryu JG, Park GR, Lee CU, Lyu SG, Sur GS, Appl. Chem., 2(1), 137 (1998)
Okada A, Kawasumi M, Usuki A, Kosima Y, Kurauchi T, Kamigaito O, Mater. Res. Soc. Symp. Proc., 171, 45 (1990)
Okada A, Kawasumi M, Kurauchi T, Kamigaito O, Polym. Prepr., 28, 447 (1987)
Lyu SG, Park YH, Rhew JH, Sur GS, J. Inst. Ind. Technol., 26, 155 (1998)
Aranda P, Ruiz-Hitzky E, Chem. Mater., 4, 1395 (1992)
Takahashi Y, Sumita L, Tadokoro H, J. Polym. Sci. B: Polym. Phys., 11, 2113 (1973)
Papke BL, Ratner MA, Schriver DF, J. Phys. Chem. Solids, 42, 493 (1981)
Tunney JJ, Detellier C, Chem. Mater., 8, 927 (1996)
Lan T, Kaviratna PD, Pinnavaia TJ, J. Phys. Chem. Solids, 57, 1005 (1996)

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[2] Lan T, Pinnavaia T, Chem. Mater., 6, 2216 (1994)

[3] Kaviratna PD, Lan T, Pinnavaia T, Polym. Prepr., 35, 788 (1994)

[4] Wang MS, Pinnavaia T, Chem. Mater., 6, 468 (1994)

[5] Kojima Y, Usuki A, Okada A, Kawasumi M, Okada A, Kurauchi T, Kumigaito O, J. Polym. Sci. A: Polym. Chem., 31, 983 (1993)

[6] Messersmith PB, Giannelis EP, J. Polym. Sci. A: Polym. Chem., 33(7), 1047 (1995)

[7] Yano K, Usuki A, Kurauchi T, Kamigaito OJ, J. Polym. Sci. A: Polym. Chem., 31, 2493 (1993)

[8] Sur GS, Ryu JG, Lyu SG, Polym. Abstract(Korea), 22(2), 139 (1997)

[9] Ryu JG, Park GR, Sur GS, Polym. Abstract(Korea), 23(1), 180 (1998)

[10] Ryu JG, Park GR, Lee CU, Lyu SG, Sur GS, Appl. Chem., 2(1), 137 (1998)

[11] Okada A, Kawasumi M, Usuki A, Kosima Y, Kurauchi T, Kamigaito O, Mater. Res. Soc. Symp. Proc., 171, 45 (1990)

[12] Okada A, Kawasumi M, Kurauchi T, Kamigaito O, Polym. Prepr., 28, 447 (1987)

[13] Lyu SG, Park YH, Rhew JH, Sur GS, J. Inst. Ind. Technol., 26, 155 (1998)

[14] Aranda P, Ruiz-Hitzky E, Chem. Mater., 4, 1395 (1992)

[15] Takahashi Y, Sumita L, Tadokoro H, J. Polym. Sci. B: Polym. Phys., 11, 2113 (1973)

[16] Papke BL, Ratner MA, Schriver DF, J. Phys. Chem. Solids, 42, 493 (1981)

[17] Tunney JJ, Detellier C, Chem. Mater., 8, 927 (1996)

[18] Lan T, Kaviratna PD, Pinnavaia TJ, J. Phys. Chem. Solids, 57, 1005 (1996)