Polymer(Korea), Vol.23, No.4, 612-616, July, 1999
투명한 전도성 복합재료 PAN/Poly(3,4-ethylenedioxythiophene)의 제조 및 물성
Preparation and Physical Properties of PAN/Poly(3,4-ethylenedioxythiophene)Transparent Conductive Composite
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초록
폴리아크릴로니트릴(PAN)을 매트릭스로 하여 투명한 전도성 고분자인 poly(3,4-ethylenedioxythiophene) (PEDOT)과의 복합재료를 제조하였다. 양이온기를 포함하는 전도성 PEDOT와 PAN과 정전기적 인력을 유도하기 위하여 PAN의 구조에 소량의 음이온기를 도입하였다. 복합재료를 제조하는데 있어서는 전도성 고분자를 매트릭스 상에서 in-situ로 중합하는 방법을 이용하였으며, 또한 이 기술을 실제 공정에 도입하기 위하여 PANWLRANF을 매트
A transparent conducting polymer composite was prepared using poly(acrylonitrile) (PAN) matrix and transparent and electrically conductive poly(3,4-ethylenedioxy thiophene)(PEDOT). In order to enhance the electrostatic interaction between the two components, a small amount of anionic group was introduced into the matrix. The conductive composite was prepated by the in-situ polymerization of EDOT in the PAN film. PAN fabric was also used a a matrix material to utilize this technique in the practical application. The presence of electrostatic interaction between conducting PEDOT and anion-containing matrix was monitored by the examination of the electrical porperties and their stability. The dyeing process was also performed on the transparent conductive fabric, and the variation of electrical property was also monitored.
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