Journal of Physical Chemistry, Vol.97, No.51, 13508-13514, 1993
1+1 Resonant Multiphoton Ionization of HI Through the First UV Continuum
We have examined resonant multiphoton ionization (REMPI) in HI using a tunable nanosecond dye laser. The parent ion, HI+, is produced by a 1+1 REMPI process with the excitation wavelength resonant with the first UV continuum. of HI. Sharp features in the wavelength-resolved spectrum of HI+ are recorded and are assigned to two-photon transitions to autoionizing Rydberg states with a finite lifetime. Differences in the two-photon spectra compared to data obtained by single-photon VUV photoionization are noted. A simple kinetic analysis of the data is employed to illuminate the mechanism of ionization and to explain the observed laser flux dependence. of the parent ion signal.
Keywords:VACUUM ULTRAVIOLET-RADIATION;SPIN-ORBIT AUTOIONIZATION;MULTI-PHOTON IONIZATION;HUND CASE E;HIGH-RESOLUTION;PHOTOELECTRON-SPECTROSCOPY;ELECTRONIC-SPECTRA;MASS-SPECTROMETRY;HYDROGEN HALIDES;METHYL-IODIDE