화학공학소재연구정보센터
Journal of Polymer Science Part B: Polymer Physics, Vol.54, No.19, 1957-1967, 2016
Comparison of mechanical and molecular measures of mobility during constant strain rate deformation of a PMMA glass
We performed constant strain rate deformation and stress relaxation on a poly(methyl methacrylate) glass at T-g - 19 K, utilizing three strain rates and initiating the stress relaxation over a large range of strain values. Following previous workers, we interpret the initial rate of decay of the stress during the relaxation experiment as a purely mechanical measure of mobility for the system. In our experiments, the mechanical mobility obtained in this manner changes by less than a factor of 3 prior to yield. During these mechanical experiments, we also performed an optical measurement of segmental mobility based on the reorientation of a molecular probe; we observe that the probe mobility increases up to a factor of 100 prior to yield. In the post-yield regime, in contrast, the mobilities determined mechanically and by probe reorientation are quite similar and show a similar dependence on the strain rate. Dynamic heterogeneity is found to initially decrease during constant strain rate deformation and then remain constant in the post-yield regime. These combined observations of mechanical mobility, probe mobility, and dynamic heterogeneity present a challenge for theoretical modeling of polymer glass deformation. (c) 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016, 54, 1957-1967