화학공학소재연구정보센터
Langmuir, Vol.32, No.35, 9097-9107, 2016
Colloidal Particles in Thin Nematic Wetting Films
We experimentally and theoretically study the variety of elastic deformations that appear when colloidal inclusions are embedded in thin wetting films of a nematic liquid crystal with hybrid anchoring conditions. In the thickest films, the elastic dipoles formed by particles and their accompanying defects share features with the patterns commonly observed in liquid crystal cells. When the film gets thinner than the particles size, however, the capillary effects strongly modify the appearance of the elastic dipoles and the birefringence patterns. The influence of the film thickness and particles sizes on the patterns has been explored. The main experimental features and the transitions observed at large scale with respect to the inclusions' size are explained with a simple two-dimensional Ansatz, combining capillarity and nematic elasticity. In a second step, we discuss the origin of the variety of observed textures. Developing a three-dimensional Landau-de Gennes model at the scale of the particles, we show that the presence of free interfaces and the beads confinement yield metastable configurations that are quenched during the film spreading or the beads trapping at interfaces.