Materials Chemistry and Physics, Vol.180, 301-313, 2016
Anodic galvanostatic polarization of AA2024-T3 aircraft alloy in conventional mineral acids
The present study is devoted to the determination of the impact of the anodization of AA2024-T3 alloys in HCl, HNO3, H2SO4 or H3PO4 on the samples' surface morphology and properties. Subsequent systematic assessments were performed by Scanning Electron Microscopy (SEM), Energy Dispersion X-Ray Spectroscopy (EDX) and X-ray Photoelectron Spectroscopy (XPS). These observations were combined with Linear Voltammetry (LVA) and Electrochemical Impedance Spectroscopy (EIS) after 48 and 168 h of exposure to a 3.5% NaCl model corrosive medium. The main result is, that completely different effects were observed in accordance to the acid used. It was established that the monoprotonic acids have a deep destructive effect due to dissolution of the alloy components, whereas the polyprotonic ones possess either indistinguishable influence, or surface film formation. (C) 2016 Elsevier B.V. All rights reserved.
Keywords:Alloy;Electrochemical techniques;Scanning Electron Microscopy (SEM);Energy Disperive X-ray Analysis (EDX);X-Ray Photoelectron Spectroscopy (XPS);Corrosion