화학공학소재연구정보센터
Materials Research Bulletin, Vol.83, 12-18, 2016
Decoration of zinc oxide nanoparticles on vertically aligned single wall carbon nanotubes: An efficient field emitter
In present work, zinc oxide (ZnO) nanoparticles are decorated on the surface of Vertically Aligned-Single Wall Carbon Nanotubes (VA-SWCNTs) to enhance field emission properties of SWCNTs. VA-SWCNTs synthesized by Plasma Enhanced Chemical Vapour Deposition (PECVD) technique are decorated with ZnO nanoparticles by thermal evaporation technique. Modified surface morphologies of as-prepared films were characterized by Atomic Force Microscope (AFM) and Raman spectroscopy to confirm the attachment of ZnO nanoparticles on VA-SWCNTs. Remarkable increase in current density, stability as well as reduction in turn on field were observed in ZnO nanoparticles coated VA-SWCNTs. Attachment of ZnO nanoparticles reduce the turn-on field of VA-SWCNTs field emitters from 2.0 to 1.0 V/mu m, while current density increase from 3.6 to 16.8 mA/cm(2) with long term stability and repeatability. The observed results are explained in terms of increased emitting area by modified surface with high field enhancement factor of VA-SWCNTs field emitters. (C) 2016 Elsevier Ltd. All rights reserved.