Journal of Physical Chemistry, Vol.98, No.5, 1386-1393, 1994
A Test of Dielectric Friction Models - Rotational Diffusion of Fluorenes in Dimethyl-Sulfoxide
The measurement of the rotational relaxation time of seven fluorene derivatives in dimethyl sulfoxide and paraffin oil is used to assess the generality of a recently proposed model of dielectric friction. This work shows that the friction experienced by these solute molecules is reproduced quite well at a qualitative level. Although agreement between the experiment and the model can also be captured by adjusting certain parameters, these adjustments are not always clearly correlated with molecular properties.
Keywords:SLIP BOUNDARY-CONDITION;PHENOXAZINE DYES;SPECTROSCOPY;DYNAMICS;REORIENTATION;COEFFICIENTS;ALCOHOLS;SOLVENTS;STILBENE;PROBES