Journal of Physical Chemistry, Vol.98, No.13, 3270-3271, 1994
Oscillating Huang-Rhys Factor in the Time-Relaxed Harmonic-Oscillator
The prediction that a charge-transfer spectrum could exhibit oscillations in the intensity has recently been confirmed experimentally. The previously introduced model of a harmonic oscillator whose frequency relaxes in time is therefore extended to include also a relaxation in position. This leads to an oscillating Huang-Rhys factor.