폴리비닐알코올과 폴리비닐알코올모노티올이 폴리초산비닐 라텍스의 안정성에 미치는 영향

이서용; 박이순; Seo Yong Lee; Lee-Soon Parkt

Polymer(Korea), Vol.24, No.5, 579-588, September, 2000

Effect of Poly(vinyl alcohol) and Poly(vinyl alcohol) Mono Thiol on the Stability Properties of Poly(vinyl acetate) Latex

이서용^†, 박이순¹

창원기능대학 환경화학과
¹경북대학교 고분자공학과

Seo Yong Lee^†, and Lee-Soon Parkt¹

Department of Environment and Chemical Technology, Changwon Polytechnic College, Changwon 641-772, Korea
¹Department of Polymer Science, Kyungpook Nat'l Univ., Taegu 702-701, Korea

E-mail:

초록

보호콜로이드에 따른 입체 안정제(steric stabilizer)작용이 폴리초산비닐(poly(vinyl acetate), PVAc)라텍스의 안정성에 미치는 영향을 조사하였다. 보호콜로이드로서 중합도 1080, 검화도 78.4%인 반응성 poly(vinyl alcohol) mono thiol(PVALT)를 사용한 것이 중합도 1100, 검화도 81.6%인 poly(vinyl alcohol)(PVA)를 사용하는 것보다 PVAc라텍스의 안정성이 양호하였으며, 반응성 PVALT의 첨가량이 증가할수록 PVAc 라텍스의 안정성은 향상되었다. PVAc 라텍스 입자의

The effects of protective colloids on the colloid stability of poly(vinyl acetate)(PVAc) latex was investigated. The stability of PVAc latex in reactive poly(vinyl alcohol) mono thiol(PVALT)(DP=1080) having 78.4% saponification value was better than poly(vinyl alcohol)(PVA)(DP=1100) having 81.6% saponification value. The colloidal stability of PVAc latex particles improved drastically with increase of the reactive PVALT. The partical surface morphology of PVAc latex was examined by trnasmission electron microscopy(TEM). It was shown that particle size of the latexes decreased with increasing reactive PVALT concentration. Therefore, the stabilities of latex for reactive PLAVT protective colloid was superior to that of PVA ones. This result is due to the introduction of many thiol froups that induce chemical bonds at PVAc latexes surface, so that the formation of PVALT-b-PVAc block copolymer via the reaction of PVAc with reactive PVALT. In addition, zeta potential of the PVAc latexes decreased with increasing sodium carbonate concentration.

Keywords:protective colloid;poly(vinyl alcohol);poly(vinyl alcohol) mono thiol;poly(vinyl acetate);latex stability

[References]

Kim MS, "Emulsion Technologies and Surface Active Agents," KAIST, Daejun, 1993 (1993)
Napper DH, "Polymeric Stabilization of Colloidal Dispersions," Academic Press, London, 1983 (1983)
Buscall R, Corner T, Stageman JF, "Polymer Colloids," Elsevier Science Pub. Co. Inc., New York, 1985 (1985)
Yang SM, Park OO, "Fundamentals of Microstructural Fluid Flow," MinEum Press, Seoul, 1997 (1997)
Shaw DJ, "Introduction to Colloid and Surface Chemistry," 4th Ed, Butterworth-Heinemann, Oxford, 1992 (1992)
Russel WB, Saville DA, Schowalter WR, "Colloidal Dispersions," Cambridge University Press, Cambridge, 1989 (1989)
Lee YK, Polym.(Korea), 3(1), 20 (1979)
Daniels WE, Enos CT, Iacoviello JG, Frost JH, Vanderhoff JW, Ahmed SM, "Proceedings of the Symposium on the Physical Chemical Properties of Colloidal Particles," ed. by R.M. Fitch, Plenum Press, New York, 1980 (1980)
Stannett V, Klein A, Litt M, Brit. Polym. J., 7, 139 (1975)
French DM, J. Polym. Sci., 32, 395 (1958)
Shirinyan VT, Mnatsakanov SS, Gromov VV, Perlova TI, Ivanchev SS, Vysokomol. Soyed, A17(1), 182 (1975)
Shirinyan VT, Mnatsakanov SS, Gromov VV, Perlova TI, Ivanchev SS, Polym. Sci. USSR, A17, 213 (1975)
Platzer N, Mod. Plastics, 23, 95 (1951)
Noro K, Brit. Polym. J., 2, 128 (1970)
Hartley F, J. Polym. Sci., 34, 397 (1959)
Traane A, J. Appl. Polym. Sci., 7, 581 (1963)
Priest WJ, J. Phys. Chem., 56, 1077 (1952)
Lee SY, Sim HS, Shin YJ, Polym.(Korea), 19(6), 883 (1995)
Lee SY, Shin YJ, Polym.(Korea), 20(2), 233 (1996)
Lee SY, Shin YJ, Polym.(Korea), 21(6), 885 (1997)
Beresniewicz A, J. Polym. Sci., 35, 321 (1959)
Varadiah VV, J. Polym. Sci., 19, 477 (1956)
Derjaguin BV, Landau L, Acta Physicochim. USSR, 14, 633 (1941)
Verwey EJW, Overbeek JG, "Theory of Stability of Lyophobic Colloids," Elsevier, Amsterdam, 1948 (1948)
Alexander AE, Napper DH, Prog. Polym. Sci., 3, 145 (1978)
Napper DH, J. Colloid Interface Sci., 45, 557 (1973)
Osmond DWJ, Vincent B, Waite FA, Colloid Polym. Sci., 253, 676 (1975)
Isaacs PK, Edelhauser HA, J. Appl. Polym. Sci., 10, 171 (1966)
Hunter RJ, "Foundation of Colloid Science," Oxford, 1987 (1987)
Frenkel J, J. Phys. USSR, 9, 385 (1945)
Lee SY, Polym.(Korea), 23(1), 91 (1999)
Matsuo M, Harashina Y, Ogita T, Polym. J., 25, 319 (1993)
Finkentscher H, Gerrens H, Schuller H, Angew. Chem., 72, 856 (1960)
Lee YP, Micale FJ, "Polymer Latexes Preparation, Characterization, and Applications," (A.C.S. Symposium series 492), eds. by E.S. Daniels, E.D. Sudol, and M.S. El-Aasser, chap. 20, A.C.S. Washington DC, 1992 (1992)
Neuhaeusler S, Richtering W, Colloids Surf. A: Physicochem. Eng. Asp., 39 (1995)

[Referenced By]

[1] Kim MS, "Emulsion Technologies and Surface Active Agents," KAIST, Daejun, 1993 (1993)

[2] Napper DH, "Polymeric Stabilization of Colloidal Dispersions," Academic Press, London, 1983 (1983)

[3] Buscall R, Corner T, Stageman JF, "Polymer Colloids," Elsevier Science Pub. Co. Inc., New York, 1985 (1985)

[4] Yang SM, Park OO, "Fundamentals of Microstructural Fluid Flow," MinEum Press, Seoul, 1997 (1997)

[5] Shaw DJ, "Introduction to Colloid and Surface Chemistry," 4th Ed, Butterworth-Heinemann, Oxford, 1992 (1992)

[6] Russel WB, Saville DA, Schowalter WR, "Colloidal Dispersions," Cambridge University Press, Cambridge, 1989 (1989)

[7] Lee YK, Polym.(Korea), 3(1), 20 (1979)

[8] Daniels WE, Enos CT, Iacoviello JG, Frost JH, Vanderhoff JW, Ahmed SM, "Proceedings of the Symposium on the Physical Chemical Properties of Colloidal Particles," ed. by R.M. Fitch, Plenum Press, New York, 1980 (1980)

[9] Stannett V, Klein A, Litt M, Brit. Polym. J., 7, 139 (1975)

[10] French DM, J. Polym. Sci., 32, 395 (1958)

[11] Shirinyan VT, Mnatsakanov SS, Gromov VV, Perlova TI, Ivanchev SS, Vysokomol. Soyed, A17(1), 182 (1975)

[12] Shirinyan VT, Mnatsakanov SS, Gromov VV, Perlova TI, Ivanchev SS, Polym. Sci. USSR, A17, 213 (1975)

[13] Platzer N, Mod. Plastics, 23, 95 (1951)

[14] Noro K, Brit. Polym. J., 2, 128 (1970)

[15] Hartley F, J. Polym. Sci., 34, 397 (1959)

[16] Traane A, J. Appl. Polym. Sci., 7, 581 (1963)

[17] Priest WJ, J. Phys. Chem., 56, 1077 (1952)

[18] Lee SY, Sim HS, Shin YJ, Polym.(Korea), 19(6), 883 (1995)

[19] Lee SY, Shin YJ, Polym.(Korea), 20(2), 233 (1996)

[20] Lee SY, Shin YJ, Polym.(Korea), 21(6), 885 (1997)

[21] Beresniewicz A, J. Polym. Sci., 35, 321 (1959)

[22] Varadiah VV, J. Polym. Sci., 19, 477 (1956)

[23] Derjaguin BV, Landau L, Acta Physicochim. USSR, 14, 633 (1941)

[24] Verwey EJW, Overbeek JG, "Theory of Stability of Lyophobic Colloids," Elsevier, Amsterdam, 1948 (1948)

[25] Alexander AE, Napper DH, Prog. Polym. Sci., 3, 145 (1978)

[26] Napper DH, J. Colloid Interface Sci., 45, 557 (1973)

[27] Osmond DWJ, Vincent B, Waite FA, Colloid Polym. Sci., 253, 676 (1975)

[28] Isaacs PK, Edelhauser HA, J. Appl. Polym. Sci., 10, 171 (1966)

[29] Hunter RJ, "Foundation of Colloid Science," Oxford, 1987 (1987)

[30] Frenkel J, J. Phys. USSR, 9, 385 (1945)

[31] Lee SY, Polym.(Korea), 23(1), 91 (1999)

[32] Matsuo M, Harashina Y, Ogita T, Polym. J., 25, 319 (1993)

[33] Finkentscher H, Gerrens H, Schuller H, Angew. Chem., 72, 856 (1960)

[34] Lee YP, Micale FJ, "Polymer Latexes Preparation, Characterization, and Applications," (A.C.S. Symposium series 492), eds. by E.S. Daniels, E.D. Sudol, and M.S. El-Aasser, chap. 20, A.C.S. Washington DC, 1992 (1992)

[35] Neuhaeusler S, Richtering W, Colloids Surf. A: Physicochem. Eng. Asp., 39 (1995)