Korean Journal of Chemical Engineering, Vol.33, No.11, 3273-3280, November, 2016
A new polymeric additive as asphaltene deposition inhibitor in CO2 core flooding
E-mail:
A new synthesized polymeric inhibitor (SPI) based on the poly-alkyl phenol formaldehyde and polyamine was introduced as asphaltene deposition inhibitor. A Turbiscan apparatus was used to investigate the stability of precipitated asphaltene in crude oil solutions by adding different concentrations of the SPI. The results of turbidity showed that the SPI could delay the asphaltene deposition and provide high stability of precipitated asphaltene in oil solutions. Then two dynamic experiments, including co-injection of crude oil and CO2 into a sandstone core, were conducted with and without the use of 500mg/L SPI at 173 bar and 50 ℃. The permeability ratio and asphaltene content remained relatively unchanged throughout the core flooding with the use of SPI, which indicated increase of the asphaltene stability in the core sample. However, the permeability ratio and outlet asphaltene content in dynamic experiment without the use of SPI decreased by about 70% and 51%, respectively.
- Narayan K, Walsh B, Fuel, 67, 215 (1988)
- Wang XQ, Gu YA, Ind. Eng. Chem. Res., 50(4), 2388 (2011)
- Babu K, Pal N, Saxena VK, Mandal A, Korean J. Chem. Eng., 33(2), 711 (2016)
- Benzagouta MS, AlNashef IM, Karnanda W, Al-Khidir K, Korean J. Chem. Eng., 30(11), 2108 (2013)
- Son H, Kim H, Lee G, Kim J, Sung W, Korean J. Chem. Eng., 31(2), 338 (2014)
- Kwon S, Lee W, Korean J. Chem. Eng., 29(6), 750 (2012)
- Zanganeh P, Ayatollahi S, Alamdari A, Zolghadr A, Dashti H, Kord S, Energy Fuels, 26(2), 1412 (2012)
- Borton D, Pinkston DS, Hurt MR, Tan X, Azyat K, Scherer A, Tykwinski R, Gray M, Qian K, Kenttamaa HI, Energy Fuels, 24, 5548 (2010)
- Buckley JS, Wang J, J. Petrol. Sci. Eng., 33, 195 (2002)
- Chang CL, Fogler HS, Langmuir, 10(6), 1749 (1994)
- Al-Sahhaf TA, Fahim MA, Elkilani AS, Fluid Phase Equilib., 194, 1045 (2002)
- Auflem IH, Havre T, Sjoblom J, Colloid Polym. Sci., 280, 695 (2002)
- Junior LCR, Ferreira MS, da Silva Ramos AC, J. Petrol. Sci. Eng., 51, 26 (2006)
- Goual L, Sedghi M, Wang XX, Zhu ZM, Langmuir, 30(19), 5394 (2014)
- Boukherissa M, Mutelet F, Modarressi A, Dicko A, Dafri D, Rogalski M, Energy Fuels, 23, 2557 (2009)
- Stephenson WK, Mercer BD, Comer DG, US Patent, 5143594 A (1992).
- Miller D, Feustel M, Vollmer A, Vybiral R, Hoffmann D, US Patent, 6180683 B1 (2001).
- Breen PJ, US Patent, 6313367 B1 (2001).
- Wilkes MF, Davies MCUS, Patent Application, 2008/0096772 (2008).
- Hu YF, Guo TM, Langmuir, 21(18), 8168 (2005)
- Karambeigi M, Kharrat R, Pet. Sci. Technol., 32, 1327 (2014)
- Ibrahim HH, Idem RO, Energy Fuels, 18(3), 743 (2004)
- Alcazar-Vara LA, Zamudio-Rivera LS, Buenrostro-Gonzalez E, Hernandez-Altamirano R, Mena-Cervantes VY, Ramirez-Perez JF, Ind. Eng. Chem. Res., 54(11), 2868 (2015)
- Ghazvini S, Nasrin MO, Nikazar M, J. Oil Gas Petrochem. Technol., 1, 57 (2014)
- Hashemi SI, Fazelabdolabadi B, Moradi S, Rashidi AM, Shahrabadi A, Bagherzadeh H, Appl Nanosci., 6, 71 (2016)
- Standard Test Method for Determination of Asphaltenes (Heptane Insolubles) in Crude Petroleum and Petroleum Products, ASTMD6560-00 (2005).
- Kraiwattanawong K, Fogler HS, Gharfeh SG, Singh P, Thomason WH, Chavadej S, Energy Fuels, 23, 1575 (2009)
- Pereira J, Delgado-Linares J, Briones A, Guevara M, Scorzza C, Salager JL, Pet. Sci. Technol., 29, 2432 (2011)
- Standard Test Method for Measuring n-Heptane Induced Phase Separation of Asphaltene-Containing Heavy Fuel Oils as Separability Number by an Optical Scanning Device, ASTMD7061-12 (2012).
- Alston RB, Kokolis GP, James CF, Soc. Petrol. Eng. J., 25, 268 (1985)
- Bahrami P, Kharrat R, Mahdavi S, Ahmadi Y, James L, Korean J. Chem. Eng., 32(2), 316 (2015)
- Bagheri M, Kharrat R, Ghotby C, Oil Gas Sci. Technol., 66, 507 (2011)
- Toth A, Szentmihalyi K, Keresztes Z, Szigyarto I, Kovacik D, Cernak M, Kutasi K, Open Chem., 13, 557 (2015)
- Jiang HQ, Sun XP, Huang MH, Wang YL, Li D, Dong SJ, Langmuir, 22(7), 3358 (2006)
- Iglesias MJ, Jimenez A, Laggoundefarge F, Suarezruiz I, Energy Fuels, 9(3), 458 (1995)
- Bodirlau R, Teaca CA, Spiridon I, BioResources, 4, 1285 (2009)
- Papadimitriou NI, Romanos GE, Charalambopoulou GC, Kainourgiakis ME, Katsaros FK, Stubos AK, J. Petrol. Sci. Eng., 57, 281 (2007)
- Bagherzadeh H, Ghazanfari MH, Kharrat R, Rashtchian D, Energy Sources Part A-Recovery Util. Environ. Eff., 36(6), 591 (2014)
- Danesh A, Krinis D, Henderson GD, Peden JM, J. Petrol. Sci. Eng., 2, 167 (1989)
- Kelland MA, Production chemicals for the oil and gas industry, CRC Press (2014).