화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.43, 127-132, November, 2016
Iron-loaded zein beads as a biocompatible adsorbent for arsenic(V) removal
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This work aims to modify zein, a corn protein, to be a biocompatible adsorbent for the removal of As(V) from water. This adsorbent was prepared by the incorporation of iron(III) chloride into 50% (w/v) of zein in ethanol and water (70:30 (v/v)) and dropping into cold water (5 °C) to form adsorbent beads. In the batch operation, various parameters, i.e., pH of solution, iron loading concentration, competing ions and adsorption time, were studied. Under the optimum conditions, the As(V) adsorption appeared to follow the Langmuir isotherm model with the maximum adsorption capacity of 1.95 mg/g.
  1. Hung DQ, Nekrassova O, Compton RG, Talanta, 64, 269 (2004)
  2. Sharma VK, Sohn M, Environ. Int., 35, 743 (2009)
  3. Sharma AK, Tjell JC, Sloth JJ, Holm PE, Appl. Geochem., 41, 11 (2014)
  4. World Health Organization, WHO Guidelines for Drinking-Water Quality, Recommendations, 4th ed., Geneva, 2011.
  5. Ministry of Science Technology and Environment, Thailand, Standards for Industrial Effluent from Factories and Industrial Estates. published in the Royal Government Gazette 113 Part 13 D, dated February 13, 1996 (B.E. 2539).
  6. Tresintsi S, Simeonidis K, Vourlias G, Stavropoulos G, Mitrakas M, Water Res., 46, 5255 (2012)
  7. Baskan MB, Pala A, Desalination, 254(1-3), 42 (2010)
  8. An B, Liang Q, Zhao D, Water Res., 45, 1961 (2011)
  9. Fogarassy E, Galambos I, Bekassy-Molnar E, Vatai G, Desalination, 240(1-3), 270 (2009)
  10. Jain CK, Singh RD, J. Environ. Manage., 107, 1 (2012)
  11. Langsch JE, Costa M, Moore L, Morais P, Bellezza A, Falcao S, J. Mater. Res. Technol., 1, 178 (2012)
  12. U.S. Environmental Protection Agency, Technologies and Costs for Removal of Arsenic from Drinking Water, 2000.
  13. Ruggieri F, Marin V, Gimeno D, Fernandez-Turiel JL, Garcia-Valles M, Gutierrez L, Eng. Geol., 101, 245 (2008)
  14. Mamindy-Pajany Y, Hurel C, Marmier N, Romeo M, C. R. Chim., 12, 876 (2009)
  15. Moharami S, Jalali M, Chem. Eng. J., 223, 328 (2013)
  16. Awual MR, El-Safty SA, Jyo A, J. Environ. Sci., 23, 1947 (2011)
  17. Shakoor MB, Niazi NK, Bibi I, Murtaza G, Kunhikrishnan A, Seshadri B, Shahid M, Ali S, Bolan NS, Ok YS, Abid M, Ali F, Crit. Rev. Environ. Sci. Technol., 46, 467 (2016)
  18. Asadullah M, Jahan I, Ahmed MB, Adawiyah P, Malek NH, Rahman MS, J. Ind. Eng. Chem., 20(3), 887 (2014)
  19. Cui H, Li Q, Gao S, Shang JK, J. Ind. Eng. Chem., 18(4), 1418 (2012)
  20. Turk T, Alp I, J. Ind. Eng. Chem., 20(2), 732 (2014)
  21. Reddy DHK, Lee SM, Yang JK, Park YJ, J. Ind. Eng. Chem., 20(5), 3658 (2014)
  22. Mahmood T, Din SU, Naeem A, Tasleem S, Alum A, Mustafa S, J. Ind. Eng. Chem., 20(5), 3234 (2014)
  23. Glocheux Y, Albadarin AB, Mangwandi C, Stewart E, Walker GM, J. Ind. Eng. Chem., 25, 56 (2015)
  24. Lin S, Wang GX, Na ZY, Lu DN, Liu Z, Chem. Eng. J., 183, 365 (2012)
  25. Chauhan D, Dwivedi J, Sankararamakrishnan N, Environ. Sci. Pollut. Res., 21, 9430 (2014)
  26. Ghorai S, Sinhamahpatra A, Sarkar A, Panda AB, Pal S, Bioresour. Technol., 119, 181 (2012)
  27. Paliwal R, Palakurthi S, J. Control. Release, 189, 108 (2014)
  28. Kim S, Xu J, J. Cereal Sci., 47, 1 (2008)
  29. Chen Y, Ye R, Liu J, Ind. Crop. Prod., 53, 140 (2014)
  30. Zhang B, Luo Y, Wang Q, Food Chem., 124, 210 (2011)
  31. Dobritoiu R, Patachia S, Appl. Surf. Sci., 285, 56 (2013)
  32. Xu H, Zhang Y, Jiang Q, Reddy N, Yang Y, J. Environ. Manage., 125, 33 (2013)
  33. Babitha S, Korrapati PS, RSC Adv., 5, 26475 (2015)
  34. Mamindy-Pajany Y, Hurel C, Marmier N, Romeo M, Desalination, 281, 93 (2011)
  35. Ngah WSW, Hanafiah MAKM, Bioresour. Technol., 99(10), 3935 (2008)
  36. Nguyen TAH, Ngo HH, Guo WS, Zhang J, Liang S, Yue QY, Li Q, Nguyen TV, Bioresour. Technol., 148, 574 (2013)
  37. Shukla MCR, Ind. Crop. Prod., 13, 171 (2001)
  38. Samiey B, Cheng CH, Wu J, Materials, 7, 673 (2014)
  39. Saha I, Gupta K, Chakraborty S, Chatterjee D, Ghosh UC, J. Ind. Eng. Chem., 20(4), 1741 (2014)
  40. Dubey SP, Nguyen TTM, Kwon YN, Lee C, J. Ind. Eng. Chem., 29, 282 (2015)
  41. Sigdel A, Park J, Kwak H, Park PK, J. Ind. Eng. Chem., 35, 277 (2016)
  42. U.S. Environmental Protection Agency, Acid Digestion of Sediments, Sludges and Soils. US EPA Method 3050B, 1996.
  43. Sanz J, Lombrana JI, de Luis AM, Ortueta M, Varona F, Environ. Chem. Lett., 1, 45 (2003)
  44. Marin-Rangel VM, Cortes-Martinez R, Villanueva RAC, Garnica-Romo MG, Martinez-Flores HE, J. Food Sci., 77, 10 (2012)