화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Polymer(Korea), Vol.40, No.6, 992-997, November, 2016
DOI10.7317/pk.2016.40.6.992  Export Citation
라디칼 중합을 이용한 폴리스티렌과 브릿지드 폴리실세스퀴옥세인 나노입자와의 유-무기 복합체 제조 및 분석
Hybrid Nanocomposites of Bridged Polysilsesquioxane Nanoparticles and Polystyrene by Radical Polymerization
하태성, 황인설, 방윤혁1, 김기영2, 임정혁, 김성룡†, 김경민†
  • 한국교통대학교 나노화학소재공학과
  • 1효성기술원
  • 2한국생산기술연구원 바이오나노섬유융합연구그룹
Tae-Sung Ha, In Seol Hwang, Yun-Hyuk Bang1, Ki-Young Kim2, Jung-Hyurk Lim, Sung-Ryong Kim†, and Kyung-Min Kim†
  • Department of Polymer Science and Engineering, Korea National University of Transportation, Chungju, Chungbuk 27469, Korea
  • 1Hyosung R&DB Labs, Anyang 14080, Korea
  • 2Department of Textile Convergence of Biotechnology & Nanotechnology, Korea Institute of Industrial Technology, Ansan 15588, Korea
E-mail:,
초록
티올 그룹을 함유한 구형의 브릿지드 폴리실세스퀴옥세인 나노입자(BPS-SH)는 bis[3-(triethoxysilyl)propyl]-disulfide를 암모니아와 알코올 용매 하에서 가수분해와 축합 반응 후 얻어진 브릿지드 폴리실세스퀴옥세인 나노입자(BPS-S-S)의 환원 반응을 통하여 제조하였다. BPS-SH와 triethylene glycol dimethacrylate(TEGDMA)에 365 nm 파장을 가진 UV를 조사하여 TEGDMA 그룹을 함유한 브릿지드 폴리실세스퀴옥세인 나노입자(BPS-TEGDMA)를 얻을 수 있었다. 합성된 BPS 나노입자는 구형의 형태를 띠고, 평균 입자크기는 200-300 nm를 나타내었다. 이렇게 얻어진 BPS-TEGDMA와 스티렌 단량체를 AIBN 개시제 하에서 중합시켜 BPS 나노입자에 폴리스티렌을 성장시킨 새로운 유-무기 복합체(BPS-TEGDMA/PS)를 합성하였다. BPS 나노입자 표면은 폴리스티렌으로 덮여있어 소수성이 증가하는 것을 확인할 수 있었다. 제조된 BPS-TEGDMA/PS의 구조 및 표면 분석은 FTIR, TGA, SEM, TEM과 같은 다양한 분석장비를 이용하여 수행하였다.
Bridged polysilsesquioxane (BPS) particles with thiol groups (BPS-SH) were prepared by the reduction of BPS particles with disulfide groups (BPS-S-S) made from hydrolysis and condensation reaction of bis[3-(triethoxysilyl) propyl]-disulfide under ammonia and alcoholic solutions. BPS-SH and triethylene glycol dimethacrylate (TEGDMA) were reacted to synthesize BPS containing TEGDMA group (BPS-TEGDMA) by UV irradiation at 365 nm. BPSTEGDMA was spherical, and the average size was around 200-300 nm. Hybrid BPS-TEGDMA/PS nanocomposites were fabricated by radical polymerization of BPS-TEGDMA and styrene with AIBN as a radical initiator. The surface of BPS-TEGDMA covered with PS increased the hydrophobicity of BPS nanoparticles. The structure and morphology of BPS-TEGDMA/PS nanocomposites were characterized by infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), scanning electron microscope (SEM), and transmission electron microscope (TEM).
Keywords:bridged polysilsesquioxane (BPS);radical polymerization;hybrid nanocomposites;UV irradiation;hydrophobicity
  1. Shea KJ, Loy DA, Chem. Mater., 13, 3306 (2001)
  2. Shea KJ, Moreau J, Loy DA, Webster O, J. Am. Chem. Soc., 114, 6700 (1992)
  3. Oviatt HW, Shea JKJ, Small JH, Chem. Mater., 5, 943 (1993)
  4. Shea KJ, Moreau J, Loy DA, Corriu RJP, Boury B, Funct. Hybrid Mater., 50, 50 (2004)
  5. Hu LC, Yonamine Y, Lee SH, van der Veer WE, Shea KJ, J. Am. Chem. Soc., 134(27), 11072 (2012)
  6. Loy DA, Beach JV, Baugher BM, Assink RA, Chem. Mater., 11, 3333 (1999)
  7. Loy DA, Shea KJ, Chem. Rev., 95(5), 1431 (1995)
  8. Jain V, Khiterer M, Montazami R, Yochum HM, Shea KJ, Heflin JR, ACS Appl. Mate. Inter., 1, 83 (2009)
  9. Lee ASS, Choi SS, Baek KY, Hwang SS, Macromol. Res., 23(1), 60 (2015)
  10. Yuen SM, Ma CCM, Teng CC, Wu HH, Kuan HC, Chiang CL, J. Polym. Sci. B: Polym. Phys., 46(5), 472 (2008)
  11. Park DS, Ha TS, Kim KY, Lim JH, Kim KM, Polym. Bull., 71(4), 819 (2014)