화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.44, 90-98, December, 2016
DOI10.1016/j.jiec.2016.08.009  Export Citation
Development of UV/H2O2/TiO2-LECA hybrid process based on operating cost: Application of an effective fixed bed photo-catalytic recycled reactor
Ali Reza Soleymani1, †, Ruhollah Chahardoli1, 2, and Massoud Kaykhaii2
  • 1Department of Applied Chemistry, Faculty of Science, Malayer University, Malayer, Iran
  • 2Department of Chemistry, Faculty of Science, University of Sistan and Baluchestan, Zahedan, Iran
E-mail:
This research describes development of a hybrid advanced oxidation processes (AOP) using a fixed bed photocatalytic hexagonal prism reactor. The beds were consisted of light expanded clay aggregates (LECA) in which nano titania particles (as photocatalyst) were coated on the LECA surface. Degradation of the direct red 16 (DR16)molecules was followed as a model pollutant in aqueous media. The influence of the nano particles and the initial pH were evaluated. The role of active species was determined and the process kinetic was studied. Also, the hybrid UV/H2O2/TiO2.LECA process with synergistic property was developed considering to both of the process efficiency and operating cost.
Keywords:LECA;Nano titania;Fixed bed;Hybrid AOP;Operating cost
  1. Andreozzi R, Caprio V, Insola A, Marotta R, Catal. Today, 53(1), 51 (1999)
  2. Lau TK, Chu W, Graham NJD, Environ. Sci. Technol., 41, 613 (2007)
  3. Chan TW, Graham NJD, Chu W, J. Hazard. Mater., 181(1-3), 508 (2010)
  4. Saien J, Soleymani AR, Sun JH, Desalination, 279(1-3), 298 (2011)
  5. Mills A, Hunte SL, J. Photochem. Photobiol. A-Chem., 108, 1 (1997)
  6. Hoffmann MR, Martin ST, Choi WY, Bahnemann DW, Chem. Rev., 95(1), 69 (1995) 
  7. Zhao J, Yang X, Build. Environ., 38, 645 (2003)
  8. Chong MN, Jin B, Chow CW, Saint C, Water Res., 44, 2997 (2010)
  9. Pelaez M, Nolan NT, Pillai SC, Seery MK, Falaras P, Kontos AG, Dunlop PSM, Hamilton JWJ, Byrne JA, O'Shea K, Entezari MH, Dionysiou DD, Appl. Catal. B: Environ., 125, 331 (2012)
  10. Thiruvenkatachari R, Vigneswaran S, Moon IS, Korean J. Chem. Eng., 25(1), 64 (2008)
  11. Saien J, Asgari M, Soleymani AR, Taghavinia N, Chem. Eng. J., 151(1-3), 295 (2009)
  12. Alexiadis A, Chem. Eng. Sci., 61(2), 516 (2006)
  13. Esterkin CR, Negro AC, Alfano OM, Cassano AE, AIChE J., 48(4), 832 (2002)
  14. Fabiyi ME, Skelton RL, J. Photochem. Photobiol. A-Chem., 132, 121 (2000)
  15. Imoberdorf GE, Irazoqui HA, Cassano AE, Alfano OM, Ind. Eng. Chem. Res., 44(16), 6075 (2005)
  16. Loddo V, Yurdakal S, Palmisano G, Gustavo EI, Horacio AI, Orlando MA, Augugliaro V, Berber H, Palmisano L, Int. J. Chem. Reactor Eng., 5, A57 (2007)
  17. Peill NJ, Hoffmann MR, Environ. Sci. Technol., 32, 398 (1998)
  18. Shang HL, Zhang ZS, Anderson WA, AIChE J., 51(7), 2024 (2005)
  19. Lee NC, Choi WY, J. Phys. Chem. B, 106(45), 11818 (2002)
  20. Liu Y, Zheng S, Du G, Shu F, Chen J, Int. J. Mod. Phys. B, 23, 1683 (2009)
  21. Beydoun D, Amal R, Low GKC, McEvoy S, J. Phys. Chem. B, 104(18), 4387 (2000)
  22. Nkansah MA, Christy AA, Barth T, Francis GW, J. Hazard. Mater., 217-218, 360 (2012)
  23. Bernhardt M, Tellesbo H, Justnes H, Wiik K, J. European Ceram. Soc., 33, 2731 (2013)
  24. Malakootian M, Nouri J, Hossaini H, Int. J. Environ. Sci. Technol., 6, 183 (2009)
  25. Ausland G, Stevik TK, Hanssen JF, Kohler JC, Jenssen PD, Water Res., 36, 3507 (2002)
  26. Shavisi Y, Sharifnia S, Zendehzaban M, Lobabi Mirghavami M, Kakehazar S, J. Ind. Eng. Chem., 20(5), 2806 (2014)
  27. Moradi H, Sharifnia S, Rahimpour F, Mater. Chem. Phys., 158, 38 (2015)
  28. Saien J, Soleymani AR, J. Ind. Eng. Chem., 18(5), 1683 (2012)
  29. Soleymani AR, Saien J, Chin S, Le HA, Park E, Jurng JG, Process Saf. Environ. Protect., 94, 307 (2015)
  30. Abdolmohammad-Zadeh H, Nejati K, Ghorbani E, Chem. Eng. Commun., 202, 1349 (2014)
  31. Boumaza S, Kaouah F, Hamane D, Trari M, Omeiri S, Bendjama Z, J. Mol. Catal. A-Chem., 393, 156 (2014)
  32. Rahimi M, Aghel B, Sadeghi M, Ahmadi M, Desalin. Water Treat., 52, 5513 (2013)
  33. Malato S, Fernandez-Ibanez P, Maldonado MI, Blanco J, Gernjak W, Catal. Today, 147(1), 1 (2009)
  34. Hosterman JW, Patterson SH, Bentonite and Fuller’s Earth Resources of the United States, Professional Paper, United States Government Printing Office, Washington, 1992.
  35. Fujishima A, Rao TN, Tryk DA, J. Photochem. Photobiol. C, 1, 1 (2000)
  36. Murashkevich A, Lavitskaya A, Barannikova T, Zharskii I, J. Appl. Spectrosc., 75, 730 (2008)
  37. Roy J, Bandyopadhyay N, Das S, Maitra S, Iran. J. Chem. Chem. Eng., 30, 65 (2011)
  38. Saniger J, Mater. Lett., 22, 109 (1995)
  39. Namduri H, Nasrazadani S, Corrosion Sci., 50, 2493 (2008)
  40. Holland MA, Pickup DM, Mountjoy G, Tsang ES, Wallidge GW, Newport RJ, Smith ME, J. Mater. Chem., 10, 2495 (2000)
  41. Daneshvar N, Aleboyeh A, Khataee AR, Chemosphere, 59, 761 (2005)
  42. Saien J, Soleymani AR, J. Hazard. Mater., 144(1-2), 506 (2007)
  43. Zhu XL, Yuan CW, Bao YC, Yang JH, Wu YZ, J. Mol. Catal. A-Chem., 229(1-2), 95 (2005)
  44. Khodja AA, Sehili T, Pilichowski JF, Boule P, J. Photochem. Photobiol. A-Chem., 141, 231 (2001)
  45. Smith MB, March J, March’s Advanced Organic Chemistry: Reactions, Mechanisms, and Structure, Wiley, New York, 2007.
  46. Beltran FJ, Rivas FJ, Gimeno O, J. Chem. Technol. Biotechnol., 80(9), 973 (2005)
  47. Lathasree S, Rao AN, SivaSankar B, Sadasivam V, Rengaraj K, J. Mol. Catal. A-Chem., 223(1-2), 101 (2004)
  48. Saien J, Khezrianjoo S, J. Hazard. Mater., 157(2-3), 269 (2008)
  49. Saien J, Delavari H, Solymani AR, J. Hazard. Mater., 177(1-3), 1031 (2010)
  50. Gozmen B, Turabik M, Hesenov A, J. Hazard. Mater., 164(2-3), 1487 (2009)
  51. Lee HJ, Kang DW, Chi J, Lee DH, Korean J. Chem. Eng., 20(3), 503 (2003)
  52. Nguyen AT, Juang RS, J. Environ. Manage., 147, 271 (2015)
  53. Zang Y, Farnood R, Top. Catal., 37, 91 (2006)
  54. Elmolla ES, Chaudhuri M, Desalination, 252(1-3), 46 (2010)
  55. Andronic L, Manolache S, Duta A, J. Nanosci. Nanotechnol., 8, 728 (2008)
  56. Sohrabi MR, Ghavami M, Desalination, 252(1-3), 157 (2010)
  57. Zarei AR, Rezaeivahidian H, Soleymani AR, Process Saf. Environ. Protect., 98, 109 (2015)
  58. Bolton JR, Bircher KG, Tumas W, Tolman CA, Pure Appl. Chem., 73, 627 (2001)
  59. US Government Energy Information Administration, Independent Statistics and Analysis, 2015 http://www.eia.gov.
  60. Chemicals Cost, 2015 http://www.alibaba.com and http://www.made-in-china.com.
  61. Li WY, Liu Y, Sun XL, Wang F, Qian L, Xu C, Zhang JP, Water Sci. Technol. Water Supply, ws2015110
  62. Dionysiou DD, Suidan MT, Baudin I, Laine JM, Appl. Catal. B: Environ., 50(4), 259 (2004)
  63. Ollis DF, Pelizzetti E, Serpone N, Environ. Sci. Technol., 25, 1522 (1991)