Lignin pyrolysis chemistry was investigated via the analysis of the products obtained from the fast pyrolysis of a pine wood at different temperatures. Methoxy phenols, such as guaiacols and eugenols, were produced mainly at 375 and 475 degrees C, while non-methoxy phenols, such as alkyl phenols and pyrocatechols were dominant at 525 and 575 degrees C. At 575 degrees C, aromatic hydrocarbons were formed together with larger amounts of light hydrocarbon gases. When the temperature was increased from 375 and 475 degrees C, the yield of pyrolytic lignin was increased, whereas its average molecular weight was decreased. At 525 degrees C, smaller molecular pyrolytic lignin with a maximum concentration of phenolic hydroxyl groups was produced due to the increased secondary cracking of the reaction intermediates. On the other hand, at 575 degrees C, larger molecular pyrolytic lignin with smaller amounts of phenolic hydroxyl groups was produced due to the increased condensation activity of the pyrolysis reaction intermediates. (C) 2016 Elsevier Ltd. All rights reserved.