화학공학소재연구정보센터
Electrochimica Acta, Vol.217, 9-15, 2016
Two - step approach of fabrication of three - dimensional reduced graphene oxide - carbon nanotubes - nickel foams hybrid as a binder -free supercapacitor electrode
A facile method is designed to prepare 3D reduced graphene oxide (rGO) - carbon nanotubes (CNTs) - nickel foams (NF). In this research, the 3D rGO-CNTs-NF electrode is fabricated by combination of electrophoretic deposition and floating catalyst chemical vapor deposition. The vertically-aligned CNTs forests not only effectively prevent stacking of rGO sheets but also facilitate the electron transfer during the charge/discharge process and contribute to the whole capacitance. Moreover, the 3D rGO-CNTs-NF hybrid can be used directly as electrodes of supercapacitor without binder. Additionally, the hybrid shows a specific capacitance of 236.18 Fg(-1) which is much higher than that of the rGO - NF electrode (100.23 Fg(-1)). Importantly, the energy density and power density of 3D rGO-CNTs-NF are respectively as high as 19.24 Wh kg(-1) and 5398 W kg(-1), indicating that our work provides a way to design hierarchical rGO-based architecture composed of rGO, CNTs and various electroactive materials for high-performance energy storage devices. (C) 2016 Elsevier Ltd. All rights reserved.