There has been growing interest in using extensive green roofs for commercial and residential buildings in urban areas. Green roofs provide many benefits, including adding an additional insulation layer. The potential of this benefit depends on many factors, including the thermal properties of the green roof substrate. Thermal conductivity values of three substrates comprised primarily of scoria, crushed roof tile and bottom-ash were measured with steady-state and transient techniques under three moisture conditions. Specific heat capacities of the green roof substrates were also measured with a transient technique. Steady-state measurements were performed with a "k-Matic" apparatus while transient measurements with KD2 Pro needles. In general, the steady-state measurements showed more consistency than transient measurements. Thermal conductivity differed among the three substrates: crushed roof tile had the highest conductivity values across all moisture contents. Substrate moisture content consistently increased thermal conductivity across all substrates, but this was significantly greater for the crushed roof tile substrate. Steady-state thermal conductivity curves were fitted using the thermal conductivity model for green roof substrates adopted by Sailor (2011). The coefficients obtained are presented and can be used in green roof models to quantify the thermal performance of green roofs and building energy savings. (C) 2016 Elsevier B.V. All rights reserved.