We have investigated the structural features of a strain-compensated InGaP/InGaP multiple-quantum well (MQW) structure on GaAs (100) substrate with a band-gap energy of around 1.7 eV for solar cell applications. In transmission electron microscopy images, noticeable thickness modulation was observed in the barrier layers for a sample grown at the substrate temperature of 530 degrees C. Meanwhile, the X-ray diffraction patterns indicated that strain relaxation predominantly occurred in the well layers. Decreasing the substrate temperature from 530 to 510 degrees C was effective in suppressing both the thickness modulation and strain relaxation. Additionally, increasing the growth rate of the well layer further suppressed the thickness modulation. In room-temperature photoluminescence (PL) emission spectra, the sample grown at 510 degrees C showed approximately 50 times higher PL peak intensity than the one grown at 530 degrees C. (C) 2016 Elsevier B.V. All rights reserved.