화학공학소재연구정보센터
Solar Energy Materials and Solar Cells, Vol.158, 202-208, 2016
Optimization of halide perovskite solar cells based on nanocolumnar ZnO
Halide perovskite solar cells based on nanocolumnar ZnO are considered alternative candidates to the more established TiO2 based devices. Replacing the scaffold oxide layer by ZnO has the benefit of a larger electron mobility and lower processing temperatures, still reaching power conversion efficiencies (PCEs) of over 15%. The perovskite layer stability and improving the PCE are currently two major issues under investigation. Regarding the latter, the presence of an interfacial layer of Al-doped ZnO (AZO) gives an enhanced power output, as it was recently reported. Using density functional theory calculations we discuss the band alignment at the ZnO (AZO) - halide perovskite interface, indicating one possible source for the enhanced PCE. (C) 2015 Elsevier B.V. All rights reserved.