This work reports on the benefits from using thin GaAsSb capping layers (CLs) on.InAs/GaAs quantum dot (QD) solar cells. The application of such CLs allows the tunability of the Q.D ground state, switching the QD-CL band alignment from type I to type II for high Sb contents and extending the photoresponse beyond 1.5 mu m. Two different structures with similar to 10% and similar to 20% Sb contents in the CL (type-I and type-II band alignments, respectively) are explored, leading to efficiency improvements over a reference InAs/GaAs QD solar cell of 20% and 10%, respectively. In general, a significant increase in short-circuit current density J(sc)) is observed, partially due to the extended photocurrent spectrum and the additional contribution of the CL itself. Particularly, for a moderate Sb content, an improved carrier collection efficiency is also found to be a main reason for the Jsc increase. Calculations from an 8 x 8 k . p method suggest the attribution of such an improvement to longer carrier lifetimes in the wetting layer-CL structure due to the transition to a type-II band alignment. Open-circuit voltages (V-oc) exceeding that of a reference QD solar cell are demonstrated under light concentration using GaAsSb CLs, which proves that the V-oc, is not limited by the low bandgap CLs. Moreover, the highest value is obtained for the high Sb content type-II structure, despite the higher accumulation of strain and the lower effective bandgap. Indeed, the faster V-oc increase with light power found in the latter case leads to an V-oc even larger than the effective bandgap. (C) 2016 Elsevier B.V. All rights reserved.