Proton conducting polymer electrolytes employed in many electrochemical pseudocapacitors are typically based on aqueous systems, which limit the operating potential and temperature range of these energy storage devices. In this study, we developed non-aqueous polymer electrolytes based on protic ionic liquids (PIL). We relied on cationic substitution to obtain proton conducting yet environmentally benign non-fluorinated ionic liquids. By developing binary systems of PILs with different cations, eutectic compositions of PILs with drastically lowered melting points were demonstrated. Through thermal analyses of these binary systems, phase diagrams were constructed which allowed us to obtain eutectic binary PIL mixtures exhibiting a liquidus range from 70 degrees C to 150 degrees C . These eutectic PIL mixtures were incorporated into polymer systems to develop non-aqueous thin film proton-conducting polymer electrolytes for solid pseudocapacitors. The proton conductivity of the eutectic ionic liquids was observed in the polymer electrolyte systems and promoted pseudocapacitive behavior in solid and liquid capacitor cells. (C) 2016 Elsevier B.V. All rights reserved.