Preparation and characterization of porous carbons from ion-exchange resins with different degree of cross-linking for hydrogen storage

Young-Woo You; Eun-Hee Moon; Iljeong Heo; Hosik Park; Ji-Sook Hong; Jeong-Kwon Suh

Journal of Industrial and Engineering Chemistry, Vol.45, 164-170, January, 2017

DOI10.1016/j.jiec.2016.09.019 Export Citation

Preparation and characterization of porous carbons from ion-exchange resins with different degree of cross-linking for hydrogen storage

Young-Woo You, Eun-Hee Moon, Iljeong Heo, Hosik Park¹, Ji-Sook Hong², and Jeong-Kwon Suh^†

Carbon Resources Institute, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu, Daejeon 305-600, Republic of Korea
¹Advanced Materials Division, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu, Daejeon 305-600, Republic of Korea
²Technology Commercialization Division, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu, Daejeon 305-600, Republic of Korea

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Porous carbons are prepared using ion-exchange resins with three different degree of cross-linking for hydrogen storage. The degree of resin cross-linking has little effect on the specific surface area and microporosity of the carbon; however, mesoporosity increases significantly with decreases in the degree of cross-linking. Porous carbon prepared from low cross-linked resin (4% cross-linking) shows a mesopore volume of 0.92 cm3/g, which is 77% higher than that from 12% cross-linked resin. The prepared carbons are used for hydrogen storage. It is found that total micropore volume is a major contributor to the high hydrogen adsorption observed at 200 bar.

Keywords:Porous carbon;Ion-exchange resin;Degree of cross-linking;Carbonization;Hydrogen storage

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