초고분자량 폴리에틸렌 그래핀옥사이드 강화복합체의 제조 및 트라이볼로지 특성연구

Xinjun Hu; Xiaojie Yan; Yu Ma; Yongxiao Bai

Polymer(Korea), Vol.41, No.1, 68-74, January, 2017

DOI10.7317/pk.2017.41.1.68 Export Citation

초고분자량 폴리에틸렌 그래핀옥사이드 강화복합체의 제조 및 트라이볼로지 특성연구

Synthesis and Tribological Performance Study of Ultrahigh Molecular Weight Polyethylene Composites Reinforced with Graphene Oxide

Xinjun Hu, Xiaojie Yan, Yu Ma, and Yongxiao Bai^†

Key Laboratory for Magnetism and Magnetic Materials, Institute of Material Science and Engineering, Lanzhou University, Lanzhou 730000, China

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In order to improve the hardness and tribological properties of ultrahigh molecular weight polyethylene (UHMWPE), UHMWPE composites reinforced with graphene oxide (GO) nanosheets by ball milling is presented in this article. The results show that the content of 20 wt% GO composite exhibits the lowest friction coefficient and the best wear resistance among all specimens under distilled water lubrication conditions. The mechanism of GO content on tribological properties of the composites under dry conditions and distilled water were investigated. Super low friction coefficient value and the best wear resistance under distilled water is attributed to water provides passivation of interacting dangling bonds on the sliding surface of GO. This study provides a new path to synthesize the high wear resistance and mechanical performance GO/UHMWPE composite materials under water condition and may have huge potential applications in many related fields, such as biomedical and marine engineering.

Keywords:nanocomposites;UHMWPE;graphene oxide;wear and friction;hardness

[References]

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Lee C, Wei X, Kysar JW, Hone J, Science, 321, 385 (2008)
Kwon S, Ko JH, Jeon KJ, Kim YH, Park JY, Nano Lett., 12, 6043 (2012)
Ansari R, Ajori S, Motevalli B, Superlattices Microstruct., 51, 274 (2012)
Penkov O, Kim HJ, Kim HJ, Kim DE, Int. J. Precis. Eng. Manu., 15, 577 (2014)
Yan C, Kim KS, Lee SK, Bae SH, Hong BH, Kim JH, Lee HJ, Ahn JH, ACS Nano, 6, 2096 (2012)
Ou JF, Wang JQ, Liu S, Mu B, Ren JF, Wang HG, Yang SR, Langmuir, 26(20), 15830 (2010)
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Bai H, Li C, Shi GQ, Adv. Mater., 23(9), 1089 (2011)
Valles C, Drummond C, Saadaoui H, Furtado CA, He M, Roubeau O, Ortolani L, Monthioux M, Penicaud A, J. Am. Chem. Soc., 130(47), 15802 (2008)
Hummers WS, Offeman RE, J. Am. Chem. Soc., 80, 1339 (1958)
Park S, An J, Piner RD, Jung I, Yang D, Velamakanni A, Nguyen ST, Ruoff RS, Chem. Mater., 20, 6592 (2008)
Lerf A, He HY, Forster M, Klinowski J, J. Phys. Chem. B, 102(23), 4477 (1998)
Bao C, Guo Y, Song L, Hu Y, J. Mater. Chem., 21, 13942 (2011)
Savage RH, J. Appl. Phys., 19, 1 (1948)
Lancaster JK, Pritchard JR, J. Phys. D-Appl. Phys., 14, 747 (1981)
Yen BK, Wear, 192, 208 (1996)
Song HJ, Zhang ZZ, Luo ZZ, Surf. Coat. Technol., 201, 2760 (2006)

[Referenced By]

[1] McGee MA, Howie DW, Neale SD, Haynes DR, Pearcy MJ, Proceedings of the Institution of Mechanical Engineers Part H-Journal of Engineering in Medicine, 211, 65 (1997)

[2] Gong GF, Yang HY, Fu X, Wear, 256, 88 (2004)

[3] Chanda A, Mukhopadhyay AK, Basu D, Chatterjee S, Ceram. Int., 23, 437 (1997)

[4] Park HJ, Kwak SY, Kwak S, Macromol. Chem. Phys., 206, 945 (2005)

[5] Xiong DS, Mater. Lett., 59, 175 (2005)

[6] Novoselov KS, Geim AK, Morozov SV, Jiang D, Zhang Y, Dubonos SV, Grigorieva IV, Firsov AA, Science, 306, 666 (2004)

[7] Geim AK, Novoselov KS, Nat. Mater., 6(3), 183 (2007)

[8] McAllister MJ, Li JL, Adamson DH, Schniepp HC, Abdala AA, Liu J, Herrera-Alonso M, Milius DL, Car R, Prud'homme RK, Aksay IA, Chem. Mater., 19, 4396 (2007)

[9] Lee C, Wei X, Kysar JW, Hone J, Science, 321, 385 (2008)

[10] Kwon S, Ko JH, Jeon KJ, Kim YH, Park JY, Nano Lett., 12, 6043 (2012)

[11] Ansari R, Ajori S, Motevalli B, Superlattices Microstruct., 51, 274 (2012)

[12] Penkov O, Kim HJ, Kim HJ, Kim DE, Int. J. Precis. Eng. Manu., 15, 577 (2014)

[13] Yan C, Kim KS, Lee SK, Bae SH, Hong BH, Kim JH, Lee HJ, Ahn JH, ACS Nano, 6, 2096 (2012)

[14] Ou JF, Wang JQ, Liu S, Mu B, Ren JF, Wang HG, Yang SR, Langmuir, 26(20), 15830 (2010)

[15] Liang H, Bu Y, Zhang J, Cao Z, Liang A, ACS Appl. Mater. Interf., 5, 6369 (2013)

[16] Bai H, Li C, Shi GQ, Adv. Mater., 23(9), 1089 (2011)

[17] Valles C, Drummond C, Saadaoui H, Furtado CA, He M, Roubeau O, Ortolani L, Monthioux M, Penicaud A, J. Am. Chem. Soc., 130(47), 15802 (2008)

[18] Hummers WS, Offeman RE, J. Am. Chem. Soc., 80, 1339 (1958)

[19] Park S, An J, Piner RD, Jung I, Yang D, Velamakanni A, Nguyen ST, Ruoff RS, Chem. Mater., 20, 6592 (2008)

[20] Lerf A, He HY, Forster M, Klinowski J, J. Phys. Chem. B, 102(23), 4477 (1998)

[21] Bao C, Guo Y, Song L, Hu Y, J. Mater. Chem., 21, 13942 (2011)

[22] Savage RH, J. Appl. Phys., 19, 1 (1948)

[23] Lancaster JK, Pritchard JR, J. Phys. D-Appl. Phys., 14, 747 (1981)

[24] Yen BK, Wear, 192, 208 (1996)

[25] Song HJ, Zhang ZZ, Luo ZZ, Surf. Coat. Technol., 201, 2760 (2006)