Measurement and correlation of the isothermal VLE data for the binary mixtures of cyclopentene (CPEN)+cyclopentyl methyl ether (CPME)

Wan Ju Jeong; Jong Sung Lim

Korean Journal of Chemical Engineering, Vol.34, No.2, 463-469, February, 2017

DOI10.1007/s11814-016-0265-5 Export Citation

Measurement and correlation of the isothermal VLE data for the binary mixtures of cyclopentene (CPEN)+cyclopentyl methyl ether (CPME)

Wan Ju Jeong, and Jong Sung Lim^†

Department of Chemical and Biomolecular Engineering, Sogang University, C.P.O. Box 1142, Seoul 04107, Korea

E-mail:

The isothermal vapor-liquid equilibrium data for the binary systems of cyclopentene (1)+cyclopentyl methyl ether (2) were measured at 313.15, 323.15, 333.15, 343.15 and 353.15 K using a dynamic-type equilibrium apparatus and online gas chromatography analysis. For all the measured VLE data consistency tests were performed for the verification of data using Barker’s method and the ASPEN PLUS Area Test method. All the resulting average absolute values of residuals [δ ln (γ1/γ2)] for Barker’s method and D values for the ASPEN PLUS area test method were comparatively small. So, the VLE data reported in this study are considered to be acceptable. This binary system shows negative deviation from Raoult’s law and does not exhibit azeotropic behavior at whole temperature ranges studied here. The measured data were correlated with the P-R EoS using the Wong-Sandler mixing rule. The overall average relative deviation of pressure (ARD-P (%)) between experimental and calculated values was 0.078% and that of vapor phase compositions (ARD-y (%)) was 0.452%.

Keywords:Vapor Liquid Equilibria (VLE);Cyclopentyl Methyl Ether (CPME);Cyclopentene (CPEN);Peng-Robinson Equation of State (PR-EoS);Wong-Sandler Mixing Rule (WS-MR)

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[2] Watanabe K, Yamagiwa N, Torisawa Y, Org. Process Res. Dev., 11, 251 (2007)

[3] Molina MJC, Mariscal R, Ojeda M, Granados ML, Bioresour. Technol., 126, 321 (2012)

[4] Ooi T, Sakai D, Takeuchi M, Tayama E, Maruoka K, Angew. Chem.-Int. Edit., 42, 5868 (2003)

[5] Kobayashi S, Kuroda H, Ohtsuka Y, Kashihara T, Masuyama A, Watanabe K, Tetrahedron, 69, 2251 (2013)

[6] Watanabe K, Molecules, 18, 3183 (2013)

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[8] Henderson RK, Gonzalez CJ, Constable DJC, Alston SR, Inglis GGA, Fisher G, Sherwood J, Blinks SP, Curzons AD, Green Chem., 13, 854 (2011)

[9] Antonucci V, Coleman J, Ferry JB, Johnson N, Mathe M, Scott JP, Xu J, Org. Process Res. Dev., 15, 939 (2011)

[10] Zhang HX, Liu GY, Li C, Zhang L, J. Chem. Eng. Data, 57(11), 2942 (2012)

[11] Oshima T, Fujiwara I, Baba Y, Solvent Extr. Res. Dev., 22, 119 (2015)

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[18] Cho H, Kim JE, Lim JS, Fluid Phase Equilib., 379, 52 (2014)

[19] Cho H, Yim JH, Lim JS, J. Supercrit. Fluids, 81, 7 (2013)

[20] Lee MH, Yim JH, Lim JS, Korean J. Chem. Eng., 29(10), 1418 (2012)

[21] Kim SA, Yim JH, Byun HS, Lim JS, Korean J. Chem. Eng., 28(12), 2324 (2011)

[22] Frenkel M, Chirico RD, Diky V, Muzny CD, Kazakov AF, NIST ThermoData Engine, NIST Standard Reference Database 103b-Pure Compounds, Binary Mixtures, and Chemical Reactions, Version 5.0, Standard Reference Data Program, National Institute of Standards and Technology, Gaithersburg, MD (2010).

[23] Smith JM, Van Ness HC, Abbott MM, Introduction to Chemical Engineering Thermodynamics, 7th Ed., McGraw-Hill, New York (2005).