Morphology of Sub-Microscale Atmospheric Aerosols composed of Two Liquid Phases According to the Loading Ratio of Organics/Water

Kee-Youn Yoo

Korean Chemical Engineering Research, Vol.55, No.1, 130-134, February, 2017

DOI10.9713/kcer.2017.55.1.130 Export Citation

Morphology of Sub-Microscale Atmospheric Aerosols composed of Two Liquid Phases According to the Loading Ratio of Organics/Water

Kee-Youn Yoo^†

Department of Chemical and Biomolecular Engineering, Seoul National University of Science and Technology, 232, Gongneung-ro, Nowon-gu, Seoul, 01811, Korea

E-mail:

Organic aerosols dispersed in the atmosphere likely undergo phase separation. Such internally mixed particles are often described as comprising an organic phase and an aqueous phase separately. We studied the morphology of two liquid separated aerosols in the sub-microscale by using a simple thermodynamic model with Russian doll geometry. The morphology of particles can be easily predicted from the simple criteria on the surface tension and two algebraic equations (the volume constraint and Young equation). This result may give the potential explanation about the complex morphology of the organic airborne particles

Keywords:Atmospheric organic aerosol;Morphology;Liquid-liquid separation;Russian doll model

[References]

Maria SF, Russell LM, Gilles MK, Myneni SCB, Science, 306, 1921 (2004)
Park SS, Cho SY, Kim SJ, Korean Chem. Eng. Res., 48(1), 20 (2010)
Pye HOT, Murphy BN, Xu L, Ng NL, Carlton AG, Guo H, Weber R, Vasilakos P, Appel KW, Budisulistiorini SH, Surratt JD, Nenes A, Hu W, Jimenez JL, Wertz GI, Misztal PK, Goldstein AH, Atmos. Chem. Phys. Discuss, doi:10.5194/acp-2016-719 (2016)
Song M, Marcolli C, Krieger UK, Zuend A, Peter T, Atmos. Chem. Phys., 12, 2691 (2012)
Zawadowicz MA, Proud SR, Seppalalinen SS, Cziczo DJ, Atmos. Chem. Phys., 15, 8975 (2015)
Shiraiwa M, Zuend A, Bertram AK, Seinfeld JH, Phys. Chem. Chem. Phys., 15, 11441 (2013)
Zhang Q, Thompson JE, GeoResJ, 3-4, 9 (2014)
De Leeuw G, Andreas EL, Anguelova MD, Fairall CW, Lewis ER, O’Dowd C, Schulz M, Schwartz SE, Rev. Geophys., doi:10.1029/2010RG000349 (2011)., 49(2)
Zuend A, Marcolli C, Peter T, Seinfeld JH, Atmos. Chem. Phys., 10, 7795 (2010)
Zuend A, Seinfeld JH, Fluid Phase Equilib., 337, 201 (2013)
Amundson NR, Caboussat A, He JW, Martynenko AV, Savarin VB, Seinfeld JH, Yoo KY, Atmos. Chem. Phys., 6, 975 (2006)
Amundson NR, Caboussat A, He JW, Martynenko AV, Seinfeld JH, J. Geophys. Res. Atmos., 112, D24S13 (2007)
Yu H, Kaufman YJ, Chin M, Feingold G, Remer LA, Anderson TL, Balkanski Y, Bellouin N, Boucher O, Christopher S, DeCola P, Kahn R, Koch D, Loeb N, Reddy MS, Schulz M, Takemura T, Zhou M, Atmos. Chem. Phys., 6, 613 (2006)
Qiu YQ, Molinero V, J. Am. Chem. Soc., 137(33), 10642 (2015)
Obeidat A, Hrahsheh F, Wilemski G, J. Phys. Chem. B, 119(29), 9304 (2015)
You Y, Renbaum-Wolff L, Carreras-Sospedra M, Hanna SJ, Hiranuma N, Kamald S, Smith ML, Zhang X, Weber RJ, Shilling JE, Dabdub D, Martin ST, Bertram AK, Proc. Nat’l Acad. Sci., 109, 13188 (2012)
Veghte DP, Bittner DR, Freedman MA, Anal. Chem., 86, 2436 (2014)
Kwamena NOA, Buajarern J, Reid JP, J. Phys. Chem. A, 114, 5787 (2010)
Vargaftik NB, Volkov BN, Voljak LD, J. Phys. Chem. Ref Data, 12(3), 817 (1983)
Goebel A, Lunkenheimer K, Langmuir, 13(2), 369 (1997)

[1] Maria SF, Russell LM, Gilles MK, Myneni SCB, Science, 306, 1921 (2004)

[2] Park SS, Cho SY, Kim SJ, Korean Chem. Eng. Res., 48(1), 20 (2010)

[3] Pye HOT, Murphy BN, Xu L, Ng NL, Carlton AG, Guo H, Weber R, Vasilakos P, Appel KW, Budisulistiorini SH, Surratt JD, Nenes A, Hu W, Jimenez JL, Wertz GI, Misztal PK, Goldstein AH, Atmos. Chem. Phys. Discuss, doi:10.5194/acp-2016-719 (2016)

[4] Song M, Marcolli C, Krieger UK, Zuend A, Peter T, Atmos. Chem. Phys., 12, 2691 (2012)

[5] Zawadowicz MA, Proud SR, Seppalalinen SS, Cziczo DJ, Atmos. Chem. Phys., 15, 8975 (2015)

[6] Shiraiwa M, Zuend A, Bertram AK, Seinfeld JH, Phys. Chem. Chem. Phys., 15, 11441 (2013)

[7] Zhang Q, Thompson JE, GeoResJ, 3-4, 9 (2014)

[8] De Leeuw G, Andreas EL, Anguelova MD, Fairall CW, Lewis ER, O’Dowd C, Schulz M, Schwartz SE, Rev. Geophys., doi:10.1029/2010RG000349 (2011)., 49(2)

[9] Zuend A, Marcolli C, Peter T, Seinfeld JH, Atmos. Chem. Phys., 10, 7795 (2010)

[10] Zuend A, Seinfeld JH, Fluid Phase Equilib., 337, 201 (2013)

[11] Amundson NR, Caboussat A, He JW, Martynenko AV, Savarin VB, Seinfeld JH, Yoo KY, Atmos. Chem. Phys., 6, 975 (2006)

[12] Amundson NR, Caboussat A, He JW, Martynenko AV, Seinfeld JH, J. Geophys. Res. Atmos., 112, D24S13 (2007)

[13] Yu H, Kaufman YJ, Chin M, Feingold G, Remer LA, Anderson TL, Balkanski Y, Bellouin N, Boucher O, Christopher S, DeCola P, Kahn R, Koch D, Loeb N, Reddy MS, Schulz M, Takemura T, Zhou M, Atmos. Chem. Phys., 6, 613 (2006)

[14] Qiu YQ, Molinero V, J. Am. Chem. Soc., 137(33), 10642 (2015)

[15] Obeidat A, Hrahsheh F, Wilemski G, J. Phys. Chem. B, 119(29), 9304 (2015)

[16] You Y, Renbaum-Wolff L, Carreras-Sospedra M, Hanna SJ, Hiranuma N, Kamald S, Smith ML, Zhang X, Weber RJ, Shilling JE, Dabdub D, Martin ST, Bertram AK, Proc. Nat’l Acad. Sci., 109, 13188 (2012)

[17] Veghte DP, Bittner DR, Freedman MA, Anal. Chem., 86, 2436 (2014)

[18] Kwamena NOA, Buajarern J, Reid JP, J. Phys. Chem. A, 114, 5787 (2010)

[19] Vargaftik NB, Volkov BN, Voljak LD, J. Phys. Chem. Ref Data, 12(3), 817 (1983)

[20] Goebel A, Lunkenheimer K, Langmuir, 13(2), 369 (1997)