화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.46, 130-138, February, 2017
DOI10.1016/j.jiec.2016.10.023  Export Citation
Structural-thermochromic relationship of polydiacetylene (PDA)/polyvinylpyrrolidone (PVP) nanocomposites: Effects of PDA side chain length and PVP molecular weight
Anothai Kamphan1, Chanita Khanantong1, Nisanart Traiphol2, and Rakchart Traiphol1, 3, †
  • 1Department of Chemistry, Faculty of Science, Naresuan University, Phitsanulok 65000, Thailand
  • 2Laboratory of Advanced Chromic Materials, Department of Materials Science, Faculty of Science, Chulalongkorn University, Bangkok 10330, Thailand
  • 3Laboratory of Advanced Polymers and Nanomaterials, School of Materials Science and Engineering and Center of Excellence for Innovation in Chemistry, Faculty of Science, Mahidol University at Salaya, Phuttamonthon 4 Road, Salaya, Nakhon Pathom 73170, Thailand
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Reversible thermochromic polydiacetylene (PDA)/polyvinylpyrrolidone (PVP) nanocomposites are prepared by using 6 diacetylene (DA) monomers. The use of relatively low molecular weight (MW) PVP provides the nanocomposites with reversible thermochromism. The shortening of PDA alkyl tail causes the decrease of color-transition temperature, ranging from 75 to 85 °C. The shortening of alkyl segment adjacent to PDA carboxylic head group, however, does not provide the same trend. The nanocomposites constituting PDAs with 8, 6 and 4 methylene units exhibits color-transition at about the same temperature. The increase of PVP MW reduces the color-transition temperature and also affects thermochromic reversibilty of the PDA/PVP nanocomposites.
Keywords:Polydiacetylene nanocomposite;Reversible thermochromism;Intercalation;Self-assemblies;Thermal sensor
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