A highly selective, sensitive and stable fluorescent chemosensor based on Schiff base and poly(azomethine-urethane) for Fe3+ ions

Musa Kamacı; Ismet Kaya

Journal of Industrial and Engineering Chemistry, Vol.46, 234-243, February, 2017

DOI10.1016/j.jiec.2016.10.035 Export Citation

A highly selective, sensitive and stable fluorescent chemosensor based on Schiff base and poly(azomethine-urethane) for Fe3+ ions

Musa Kamacı^{1, 2}, and Ismet Kaya^{1, 3, †}

¹Polymer Synthesis and Analysis Lab., Department of Chemistry, Canakkale Onsekiz Mart University, 17020, Canakkale, Turkey
²Faculty of Sciences and Letters, Department of Chemistry, Piri Reis University, 34940 Tuzla, Istanbul, Turkey
³, Turkey

E-mail:

In this paper, Schiff base (PAH) and its poly(azomethine-urethane) derivative (P-PAH) were synthesized and high-quality film sensor of these compounds could be easily fabricated on transparent polyester surface through dip-coating technique. Then, these films were used as fluorescence probes for the detection of metal ions in aqueous solutions. Photophysical properties of fluorescent films were investigated using fluorescence and UV-vis spectrometers. Fluorescence properties of probes were investigated in the presence of a series of differentmetal ions and the results showed thatmonomer and polymer films have a highly sensitive and selective response to Fe3+ ion in deionized water. Moreover, fluorescence measurements showed that the prepared fluorescent films have in the range 143-180 nm Stokes shift value. Also, contact angles of film probes were investigated and contact angles of PAH and PPAH probes measured as 85 ± 1 and 95 ± 2°, respectively.

Keywords:Fluorescent probe;Fe (III) sensor;Polymer film;Chemosensor;Poly(azomethine-urethane);Contact angle’s

[References]

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Kaya I, Yıldırım M, Kamacı M, Synth. Met., 161, 2036 (2011)
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Kamacı M, Kaya I, J. Inorg. Organomet. Polym., 25, 1250 (2015)
Kaya I, Kamacı M, Prog. Org. Coat., 74, 204 (2012)
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Roy N, Dutta A, Mondal P, Paul PC, Singh TS, J. Lumines., 165, 167 (2015)
Liu HY, Synth. React. Inorg. Met-Org. Chem., 46, 210 (2016)
Kamacı M, Kaya I, J. Macromol. Sci.-Pure Appl. Chem., 51, 805 (2014)
Niu MJ, Li Z, Chang GL, Kong XJ, Hong M, Zhang Q, PLoS One, 10, e01309 (2015)

[Referenced By]

[1] Carter KP, Young AM, Palmer AE, Chem. Rev., 114(8), 4564 (2014)

[2] Sareen D, Kaur P, Singh K, Coord. Chem. Rev., 265, 125 (2014)

[3] Kim H, Lee M, Kim HJ, Kim JS, Yoon J, Chem. Soc. Rev., 37, 1465 (2008)

[4] Zhang Y, Adeloju SB, Anal. Chim. Acta, 22 (2012)

[5] Xiang G, Li L, Jiang X, He L, Fan L, Anal. Lett., 4, 706 (2013)

[6] Liu J, Lu Y, J. Fluoresc., 14, 343 (2004)

[7] Lee JH, Wang ZD, Liu JW, Lu Y, J. Am. Chem. Soc., 130(43), 14217 (2008)

[8] Wright AT, Anslyn EV, Chem. Soc. Rev., 35, 14 (2006)

[9] Yang XH, Li S, Tang ZS, Yu XD, Huang T, Gao Y, Chin. Chem. Lett., 26, 129 (2015)

[10] Greenwood NN, Earnshaw A, Chemistry of the Elements, Pergamon Press, Oxford, 1984p. 1071.

[11] Chen X, Hong H, Han R, Zhang D, Ye Y, Zhao Y, J. Fluoresc., 22, 789 (2012)

[12] He L, Liu C, Xin JH, Sens. Actuators B-Chem., 213, 181 (2015)

[13] Kamacı M, Kaya I, J. Inorg. Organomet. Polym., 25, 1250 (2015)

[14] Mikata Y, Nakanishi K, Nakagaki F, Kizu A, Konno H, Eur. J. Inorg. Chem., 22, 3769 (2015)

[15] Aisen P, Wessling-Resnick M, Leibold EA, Curr. Opin. Chem. Biol., 3, 200 (1999)

[16] Burdo JR, Connor JR, Biometals, 16, 63 (2003)

[17] Meng WF, Yang MP, Li B, Cheng Z, Yang BQ, Tetrahedron, 70, 8577 (2014)

[18] Sui B, Tang S, Liu T, Kim B, Belfield KD, ACS Appl. Mater. Interfaces, 6, 18408 (2014)

[19] Kaya I, Kamacı M, J. Fluoresc., 23, 115 (2013)

[20] Kamacı M, Kaya I, J. Fluoresc., 25, 1339 (2015)

[21] Kaya I, Yıldırım M, Kamacı M, Synth. Met., 161, 2036 (2011)

[22] Avcı A, Kaya I, Tetrahedron Lett., 56, 1820 (2015)

[23] Kamacı M, Kaya I, J. Inorg. Organomet. Polym., 25, 1250 (2015)

[24] Kaya I, Kamacı M, Prog. Org. Coat., 74, 204 (2012)

[25] Faraji S, Krylov AI, J. Phys. Chem. B, 119(41), 13052 (2015)

[26] Zhang XF, Zhang J, Liu L, J. Fluoresc., 24, 819 (2014)

[27] Sarkar D, Pramanik AK, Mondal TK, RSC Adv., 4, 25341 (2014)

[28] Tian ZY, Song LN, Zhao Y, Zang FL, Zhao ZH, Chen NH, Xu XJ, Wang CJ, Molecules, 20, 16491 (2015)

[29] Roy N, Dutta A, Mondal P, Paul PC, Singh TS, J. Lumines., 165, 167 (2015)

[30] Liu HY, Synth. React. Inorg. Met-Org. Chem., 46, 210 (2016)

[31] Kamacı M, Kaya I, J. Macromol. Sci.-Pure Appl. Chem., 51, 805 (2014)

[32] Niu MJ, Li Z, Chang GL, Kong XJ, Hong M, Zhang Q, PLoS One, 10, e01309 (2015)