Encapsulation of Carbon Black by Surfactant Free Emulsion Polymerization Process

Jatindranath Maiti; Ahmed Ali Basfar

Macromolecular Research, Vol.25, No.2, 120-127, February, 2017

DOI10.1007/s13233-017-5023-y Export Citation

Encapsulation of Carbon Black by Surfactant Free Emulsion Polymerization Process

Jatindranath Maiti, and Ahmed Ali Basfar^†

Radiation Technology Center, Atomic Energy Research Institute, King Abdulaziz City for Science and Technology (KACST), P.O. Box 6086, Riyadh 11442, Saudi Arabia

E-mail:

The drive to remove emulsion polymerization’s dependence on surfactant, while obtaining stable and homogeneous latex after polymerization is of vital importance in the coming decades due to the disadvantage of contamination of the final product by emulsifier. Carbon black encapsulation by surfactant free emulsion polymerization was investigated. Polymer of sodium sulfonated styrene - styrene - butylacrylate was synthesized in presence of carbon black at various concentrations. Monomer conversion and solid content were calculated. 1H NMR, DSC, GPC, DLS, SEM, and TEM were used to characterize the latex particle. The effect of PEG on particle size, reaction behavior, and polymer properties of final latex particles was investigated. Latex particle size in the range of 120-150 nm with low PDI is obtained. Spherical shape with core shell structure of CB encapsulated polymer particle with homogeneous distribution is observed in SEM and TEM micrographs.

Keywords:carbon black encapsulation;core-shell particle;surfactant free emulsion polymerization

[References]

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Weiss CK, Landfester K, Adv. Polym. Sci., 233, 185 (2010)
Khan AK, Ray BC, Maiti J, Dolui SK, Pigment Resin Technol., 38, 159 (2009)
Liu HB, Wen SG, Wang JH, Zhu Y, J. Appl. Polym. Sci., 123(6), 3255 (2012)
Nguyen D, Zondanos HS, Farrugia JM, Serelis AK, Such CH, Hawkett BS, Langmuir, 24, 2140 (2012)
Tiarks F, Landfester K, Antonietti M, Macromol. Chem. Phys., 202, 51 (2001)
Han H, Lee J, Park DW, Shim SE, Macromol. Res., 18(5), 435 (2010)
Casado RA, Lovell PA, Navabpour P, Stanford JL, Polymer, 48(9), 2554 (2007)
Chen AK, Cheng CM, Lawrynowicz GEK, 2001, EP 1088833 A1.
Nagai K, Igarashi Y, Taniguchi T, Colloids Surf. A: Physicochem. Eng. Asp., 153, 161 (1999)
Zhang R, Guo L, Zhang M, Wen H, Zhao D, Chen Q, Polym. Prepr Am. Chem. Soc. Division of Polymer Chemistry, 45, 1036 (2004)
Zhou Y, Zhang Q, Liu Y, Wang W, Colloid Polym. Sci., 291, 2399 (2013)
Li Q, Wu G, Zhang X, Wu C, Polym. J., 38, 1245 (2006)
Kiatkamjornwong S, Pomsanam P, J. Appl. Polym. Sci., 89(1), 238 (2003)
Lee J, Hong CK, Choe S, Shim SE, J. Colloid Interface Sci., 310(1), 112 (2007)
Arunbabu D, Sanga Z, Seenimeera KM, Jana T, Polym. Int., 58, 88 (2009)
De la Fuente JL, Fernandez-Garcia M, Madruga EL, J. Appl. Polym. Sci., 80(5), 783 (2001)
Shi YM, Shan GR, Shang Y, Langmuir, 29(9), 3024 (2013)
Park YH, Kim WS, Lee DW, Anal. Bioanal. Chem., 375, 489 (2003)
Studart AR, Amstad E, Gauckler LJ, Langmuir, 23, 1081 (2003)
Zhang F, Cao L, Yang W, Macromol. Chem. Phys., 211, 744 (2010)
Qiu D, Cosgrove T, Howe AM, Macromol. Chem. Phys., 206, 2233 (2005)

[Referenced By]

[1] Steiert N, Landfester K, Macromol. Mater. Eng., 292, 1111 (2007)

[2] Weiss CK, Landfester K, Adv. Polym. Sci., 233, 185 (2010)

[3] Khan AK, Ray BC, Maiti J, Dolui SK, Pigment Resin Technol., 38, 159 (2009)

[4] Liu HB, Wen SG, Wang JH, Zhu Y, J. Appl. Polym. Sci., 123(6), 3255 (2012)

[5] Nguyen D, Zondanos HS, Farrugia JM, Serelis AK, Such CH, Hawkett BS, Langmuir, 24, 2140 (2012)

[6] Tiarks F, Landfester K, Antonietti M, Macromol. Chem. Phys., 202, 51 (2001)

[7] Han H, Lee J, Park DW, Shim SE, Macromol. Res., 18(5), 435 (2010)

[8] Casado RA, Lovell PA, Navabpour P, Stanford JL, Polymer, 48(9), 2554 (2007)

[9] Chen AK, Cheng CM, Lawrynowicz GEK, 2001, EP 1088833 A1.

[10] Nagai K, Igarashi Y, Taniguchi T, Colloids Surf. A: Physicochem. Eng. Asp., 153, 161 (1999)

[11] Zhang R, Guo L, Zhang M, Wen H, Zhao D, Chen Q, Polym. Prepr Am. Chem. Soc. Division of Polymer Chemistry, 45, 1036 (2004)

[12] Zhou Y, Zhang Q, Liu Y, Wang W, Colloid Polym. Sci., 291, 2399 (2013)

[13] Li Q, Wu G, Zhang X, Wu C, Polym. J., 38, 1245 (2006)

[14] Kiatkamjornwong S, Pomsanam P, J. Appl. Polym. Sci., 89(1), 238 (2003)

[15] Lee J, Hong CK, Choe S, Shim SE, J. Colloid Interface Sci., 310(1), 112 (2007)

[16] Arunbabu D, Sanga Z, Seenimeera KM, Jana T, Polym. Int., 58, 88 (2009)

[17] De la Fuente JL, Fernandez-Garcia M, Madruga EL, J. Appl. Polym. Sci., 80(5), 783 (2001)

[18] Shi YM, Shan GR, Shang Y, Langmuir, 29(9), 3024 (2013)

[19] Park YH, Kim WS, Lee DW, Anal. Bioanal. Chem., 375, 489 (2003)

[20] Studart AR, Amstad E, Gauckler LJ, Langmuir, 23, 1081 (2003)

[21] Zhang F, Cao L, Yang W, Macromol. Chem. Phys., 211, 744 (2010)

[22] Qiu D, Cosgrove T, Howe AM, Macromol. Chem. Phys., 206, 2233 (2005)