화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.47, 348-359, March, 2017
DOI10.1016/j.jiec.2016.12.005  Export Citation
Extractive-oxidative removals of dibenzothiophene and quinoline using vanadium substituted Dawson emulsion catalyst and ionic liquid based solvents
F. Banisharif, M.R. Dehghani†, M.C. Capel-Sanchez1, and J.M. Campos-Martin1
  • School of Chemical Engineering, Iran University of Science and Technology, Narmak, Tehran, Iran
  • 1Grupo de Energía y Química Sostenibles (EQS) Instituto de Catálisis y Petroleoquímica, CSIC, Marie Curie, 2, Cantoblanco, 28049 Madrid, Spain
E-mail:
Extractive-catalytic oxidative desulfurization (ECODS) of model diesel using vanadium substituted Dawson-type emulsion catalyst has been investigated for the first time. At different operational conditions, ECODS was studied using selected solvents and [cetrimonium]11P2W13V5O62 by means of Taguchi methods Under the optimized conditions (ionic liquids/oil volume ratio 1:8, 7.5 g/L catalyst, O/S mole ratio 8, T = 70 °C after 45 min) 94% of sulfur and 100% of quinoline were removed. It is worth mentioning that in the presence of catalyst, solvent/oil volume decreases by 45% while sulfur removal increases by 54% compared to extraction desulfurization.
Keywords:Desulfurization;Denitrogenation;Oxidation-extraction;Emulsion catalyst;Ionic liquid
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