화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.34, No.3, 701-705, March, 2017
DOI10.1007/s11814-016-0310-4  Export Citation
Oxidation of tetralin to 1-tetralone over CrAPO-5
Samiran Bhattacharjee, Yu-Ri Lee1, and Wha-Seung Ahn1, †
  • Centre for Advanced Research in Sciences (CARS), University of Dhaka, Dhaka 1000, Bangladesh, Korea
  • 1Department of Chemical Engineering, Inha University, Incheon 22212, Korea
E-mail:
A chromium-incorporated microporous aluminophosphate, CrAPO-5, was tested as a catalyst for the oxidation of tetralin using either a combination of aldehyde and O2 (1 atm) or tert-butyl hydroperoxide as an oxidant system. The former resulted in significantly improved catalytic performance (69.6% yield to 1-tetralone) over the latter (38.5% yield to 1-tetralone) at 80 °C in 8 h, and conversion increased in the sequence of acetaldehyde<
Keywords:CrAPO-5;Tetralin Oxidation;Pivalaldehyde;Acylperoxy Radicals;Tert-butyl Hydroperoxide
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