화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.34, No.3, 928-934, March, 2017
DOI10.1007/s11814-016-0339-4  Export Citation
Cycloaddition of carbon dioxide with propylene oxide using zeolitic imidazolate framework ZIF-23 as a catalyst
Hyeongseok Ryu, Roshith Roshan, Moon-Il Kim1, Dong-Woo Kim1, Manickam Selvaraj2, and Dae-Won Park†
  • School of Chemical and Biomolecular Engineering, Pusan National University, Busan 46241, Korea
  • 1Korea Research Institute of Chemical Technology, Ulsan 44412, Korea
  • 2Nanotechnology and Catalysis Research Center, University of Malaya, Kuala Lumpur 50603, Malaysia
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Zeolitic imidazolate framework ZIF-23 was prepared and used as catalyst for the solventless synthesis of cyclic carbonate from CO2 and propylene oxide with or without TBAB co-catalyst. ZIF-23 catalysts were prepared by a solvothermal or microwave method and they were characterized by various physicochemical techniques such as XRD, FT-IR, BET, TGA, and FE-SEM. The effects of reaction parameters such as temperature, reaction time, CO2 pressure, and co-catalyst on the reactivity of catalyst were investigated. ZIF-23 was recyclable up to four times without any considerable loss of its initial activity. Reaction mechanism containing the role of ZIF-23 with TBAB co-catalyst was also proposed.
Keywords:Zeolitic Imidazolate Framework;ZIF-23;Cycloaddition;Propylene Oxide;CO2
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