Here we report an Ag3PO4@PANI visible photocatalyst with core@shell structure prepared by a chemisorption method. The photocatalytic activity of Ag3PO4@PANI was enhanced significantly with increasing proportion of PANI. The high photocatalytic performance for the degradation of phenol and 2,4-dichlorophenol over Ag3PO4@PANI (5 wt.%) composite photocatalyst reached 100% and 95.3%, which were 1.44 and 1.38 times of that of bulk Ag3PO4, respectively. The photo catalytic activity of Ag3PO4@PANI remained 85% after five cycling runs, whereas the activities of M-Ag3PO4/PANI (5 wt.%) and Ag3PO4 remained 42% and 24%, respectively, indicating that Ag3PO4@PANI photocatalyst possessed a superior stability. Further analyses showed that the enhancement of photocatalytic activity and photo-stability originated from the superior charge mobility derived from the 7-conjugated structure of PANI and the hybridization effect arising from Ag3PO4 and PANI. Moreover, the matched energy level between PANI and Ag3PO4 led to the efficient separation and transfer of photo-generated electron-hole at their interface, thus improving the photocatalytic performance of Ag3PO4@PANI composite. In addition, PANI shell can prevent the dissolution of Ag3PO4 particles in aqueous solution during the photocatalytic reaction, resulting in a high stability of the Ag3PO4@PANI composite photocatalyst. (C) 2016 Elsevier B.V. All rights reserved.