화학공학소재연구정보센터
Applied Surface Science, Vol.392, 549-556, 2017
Comparison study of transparent RF-sputtered ITO/AZO and ITO/ZnO bilayers for near UV-OLED applications
Hybrid inorganic/organic light-emitting diodes have attracted much attention in the field of luminescent electronics due to the desired incorporation of high optoelectronic features of inorganic materials with the processability and variety of organic polymers. To generate and emit a near ultraviolet (N-UV) ray, wide band gap semiconductors can be applied in the organic light-emitting diodes (OLEDs). In this paper, zinc oxide (ZnO) and aluminum-doped ZnO (AZO) thin films are deposited by radio frequency (RF) sputtering above the ITO electrode and poly [2-methoxy-5-(2-ethyl-hexyloxy)-1,4-phenylene-vinylene] (MEH-PPV) conjugated polymer is utilized as a complementary p-type semiconductor in OLED structure. The impact of ZnO and AZO thickness on the structural, electrical, optical and morphological properties of ITO/AZO and ITO/ZnO bilayers are scrutinized and compared. Results show that with the enlargement of both ZnO and AZO film thickness, the physical properties are gradually improved resulting in the better quality of transparent conducting thin film. The average electrical resistivity of 8.4 x 10(-4) and 1.1 x 10(-3) Omega-cm, average sheet resistance of 32.9 and 42.3 Omega/sq, average transmittance of 88.3 and 87.3% and average FOM of 1.0 x 10(4) and 7.4 x 10(3) (Omega-cm)(-1) are obtained for ITO/AZO and ITO/ZnO bilayers, respectively. Moreover, comparing the results indicates that the strain and the stress within the ITO/AZO bilayer are decreased nearly 19% with respect to ITO/ZnO bilayer which yield higher quality of crystal. Consequently, the physical properties of ITO/AZO bilayer is found to be superior regarding ITO/ZnO bilayer. For fabricated UV-OLEDs, the turn-on voltages, the characteristic energy (Et) and the total concentration of traps (N-t) for the devices with the structures of ITO/ZnO/MEH-PPV/Al and ITO/AZO/MEH-PPV/Al are obtained 12 and 14 V, 0.108 and 0.191 eV, 9.33 x 10(16) and 5.22 x 10(16) cm(-3), respectively. Furthermore, according to the electroluminescence (EL) spectra, the near band emission (NBE) peak for device with the structure of ITO/ZnO/MEH-PPV/Al is attained nearly in the wavelengths of 408 nm which is in N-UV region. For ITO/AZO/MEH-PPV/Al, a slightly blue shift in NBE peak is observed due to the Burstein-Moss (BM) effect. Ultimately, different charge carrier transport mechanisms of fabricated UV-OLEDs have been carefully investigated. (C) 2016 Elsevier B.V. All rights reserved.