Intermolecular C-O Coupling Using Hemicucurbituril Supported Ionic Liquid Phase Catalyst

Kurane R; Bansode P; Khanapure S; Kale D; Salunkhe R; Rashinkar G

Catalysis Letters, Vol.146, No.12, 2485-2494, 2016

DOI10.1007/s10562-016-1871-x Export Citation

Intermolecular C-O Coupling Using Hemicucurbituril Supported Ionic Liquid Phase Catalyst

Kurane R, Bansode P, Khanapure S, Kale D, Salunkhe R, Rashinkar G

Hemicucurbituril supported ionic liquid phase catalyst (HmCucSILP) has been synthesized by anchoring multilayer of ionic liquid ([Bmim]Cl) containing Pd(OAc)(2) and X-phos on the surface of hemicucurbit[6]uril. The HmCucSILP was effectively employed in intermolecular C-O coupling of aryl halides with sodium alkoxides for the synthesis of alkyl aryl ethers. [GRAPHICS] .

Keywords:Hemicucurbituril;Intermolecular C-O coupling;Alkyl aryl ethers;X-Phos;Reusability