화학공학소재연구정보센터
Catalysis Today, Vol.282, 140-150, 2017
Titania nanotubes decorated with anatase nanocrystals as support for active and stable gold catalysts for CO oxidation
Gold nanoparticles supported on titania nanostructured materials were prepared, characterized and tested in CO oxidation. Two nanostructured supports were used: titania nanotubes (TNT) synthesized by the Kasuga method and titania nanotubes decorated with TiO2 anatase nanocrystals prepared by post-synthetic treatment of TNT with 0.05 M HNO3 solution at 70 degrees C for 48 h (TNT-T). Gold catalysts with 4 wt.% of Au nominal loading were prepared by deposition-precipitation with urea. A reference Au catalyst supported on TiO2 Degussa P-25 was also prepared. Supports and catalysts were characterized by N-2 physisorption, XRD, UV-vis and Raman spectroscopy, TPR, SEM-EDX and HRTEM. HRTEM characterization showed that gold nanoparticles with an average size between 2 and 7 nm were obtained in all catalysts making them suitable for CO oxidation. Catalytic tests showed differences in activity and stability among the prepared catalysts. The Au/TNT catalyst presented poor activity for CO oxidation, meanwhile the Au/TNT-T catalyst showed higher activity than the Au/TiO2 Degussa P-25, especially at a low temperature interval (-10 to 100 degrees C). Stability tests performed for Au/TNT-T and Au/TiO2 Degussa P-25 catalysts at 25 degrees C revealed higher stability of the Au/TNT-T catalyst, attributed to low sintering of gold nanoparticles. (C) 2016 Elsevier B.V. All rights reserved.