Simulated solid waste was incinerated in a fixed bed, while continuously collecting volatized Pb and Cd to investigate the dynamic volatilization behavior. The dynamic data revealed the reducing atmosphere generated by the fixed bed as the main reason for the lower initial volatilization temperatures of Pb and Cd compared to PbO and CdO melting points during chlorine-free incineration. CdO was easier to reduce than PbO; consequently, Cd volatilized stronger than Pb in the chlorine-free fixed bed. However, CdO volatilization was expected to be weaker than PbO volatilization in an air atmosphere. In contrast to the reduction in a fixed bed, the addition of PVC led to indirect chlorination of Pb and Cd at 300-400 degrees C and 400-500 degrees C, respectively and their volatilization was significantly enhanced via chlorination. NaCl directly chlorinated Pb and Cd at comparatively high temperatures of 800-900 degrees C and 700-800 degrees C, respectively via involvement of SiO2 and Al2O3. Moreover, CaO absorbed HCl from PVC, resulting in volatilization inhibition of Pb and Cd at a temperature below 700 degrees C. However, chlorine was released at a higher temperature. Furthermore, CaO had no effect on NaCl-induced volatilization enhancement of Pb and Cd. (C) 2016 Elsevier Ltd. All rights reserved.