Journal of Physical Chemistry, Vol.99, No.16, 5765-5768, 1995
Diffusion of Pseudoplanar Solutes - An Investigation on the Effects of Hydrogen-Bonding
Mutual diffusion coefficients of pseudoplanar molecules capable of forming hydrogen bonds at infinite dilution in various solvents have been measured at 298.2 K using Taylor’s dispersion method. The data are compared with those of the nonassociated pseudoplanar solutes reported in the literature and also here. Solutes capable of strong solute-solvent interactions in this study are found to diffuse slower than the nonassociated ones with similar size and shape. The effects of hydrogen bonding on diffusion are reported and discussed.
Keywords:BINARY-LIQUID MIXTURES;ROTATIONAL COUPLING PARAMETERS;PARTICLE CORRELATION-FUNCTIONS;HARD-SPHERE THEORY;TRACER DIFFUSION;SELF-DIFFUSION;MUTUAL DIFFUSION;AROMATIC-HYDROCARBONS;POLYATOMIC LIQUIDS;TEMPERATURE-DEPENDENCE