Polyvinyl chloride (PVC) containing chlorine can release highly toxic materials and persistent organic pollutants if improperly disposed of. The combined technique of powder activated carbon (PAC) coating and mild heat treatment has been found to selectively change the surface hydrophobicity of PVC, enhancing its wettability and thereby promoting its separation from heavy plastic mixtures included polycarbonate (PC), polymethyl methacrylate (PMMA), polystyrene (PS) and acrylonitrile butadiene styrene (ABS) by means of froth flotation. The combined treatments helped to rearrange the surface components and make PVC more hydrophobic, while the remaining plastics became more hydrophilic. After the treatments at 150 degrees C for 80s the contact angle of the PVC was greatly increased from 90.5 to 97.9 degrees. The SEM and AFM reveal that the surface morphology and roughness changes on the PVC surface. XPS and FT-IR results further confirmed an increase of hydrophobic functional groups on the PVC surface. At the optimized froth flotation and subsequent mixing at 150 rpm, 100% of PVC was recovered from the remaining plastic mixture with 93.8% purity. The combined technique can provide a simple and effective method for the selective separation of PVC from heavy plastics mixtures to facilitate easy industrial recycling. (C) 2016 Elsevier B.V. All rights reserved.