Journal of Polymer Science Part A: Polymer Chemistry, Vol.55, No.1, 93-106, 2017
Polymerization of mono-, Di-, and trichloroethyl methacrylates: A study in chain transfer
Bulk free radical polymerization of the monomer series CH2=C(CH3)C(O)OCH2CH3-nCln, n=1, 2, 3, yields an unexpectedly crosslinked product with a crosslink density that increases with decreasing chlorine content of the respective monomer (n=3