Solar Energy, Vol.141, 242-248, 2017
Plasmonic luminescent down shifting layers for the enhancement of CdTe mini-modules performance
In this investigation, plasmonic coupling between luminescent species (lumogen yellow, and silver nanoparticles (Ag NPs) has been exploited to produce significant enhancement in absorption and fluorescence emission of lumogen yellow dye luminescent downshifting (LDS) layers. The optimum dye concentration in a poly(methyl,methacrylate) polymer LDS layer of 100 p.m thickness was established. Subsequently, plasmonic coupling with Ag NPs was introduced and optimum concentration has been determined for the composite plasmonic Luminescent Down-Shifting (pLOS) layers. The optimum plasmonic coupling has been observed to produce fluorescence emission enhancement of up to 81% for the dye-pLDS layers. The pLDS layers were deposited on top of CdTe mini-modules to investigate the action of plasmonic interaction in LDS layers. It has been demonstrated that the addition of pLDS layers containing lumogen yellow dye increases the short circuit current density (J(SC)) of CdTe devices between 300 and 500 nm. An increase of similar to 100% has been achieved. External quantum efficiency (EQE) measurements of the pLDS layers have also shown significant improvement below 500 nm reaching 25-40%, while increased efficiency was confirmed with current-voltage (J-V) measurements. (C) 2016 Elsevier Ltd. All rights reserved.
Keywords:Spectral losses;Luminescent down-shifting (LDS);Lumogen yellow;Plasmonic;Silver nanoparticles (Ag NPs);Plasmonic Luminescent Down-Shifting (pLDS) layers;Surface plasmon resonance (SPR);Photovoltaics;CdTe mini modules