화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Clean Technology, Vol.23, No.1, 1-14, March, 2017
DOI10.7464/ksct.2017.23.1.001  Export Citation
수용액으로부터 질산성질소 제거를 위한 기술
Separation Technologies for the Removal of Nitrate-Nitrogen from Aqueous Solution
서양곤1, †, 정세영2, 3
  • 1경상대학교 화학공학과/공학연구원, 52828 경남 진주시 진주대로 501
  • 2창녕군개발공사, 50320 경남 창녕군 대지면 우포유어농로 642-12
  • 3경상대학교 대학원 환경보전학과, 52828 경남 진주시 진주대로 501
Yang Gon Seo1, †, and Se Yeong Jung2, 3
  • 1Department of Chemical Engineering/ERI, Gyeongsang National University, 501 Jinju-daero, Jinju-si, Gyeongsangnam-do 52828, Korea
  • 2Changnyeong-gun Development Corporation, 642-12 Upoyueonong-ro, Daeji-myeon, Changnyeong-gun, Gyeongsangnam-do 50320, Korea
  • 3Department of Environment Protection, Graduate School, Gyeongsang National University, 501 Jinju-daero, Jinju-si, Gyeongsangnam-do 52828, Korea
E-mail:
초록
높은 농도의 질산염을 포함하는 물은 인간의 건강을 위협하고 부영양화의 원인이 되기 때문에 제한 농도 이하로 처리되어야 한다. 그러나 질산염은 수용액에서의 높은 용해도로 인해 응집, 여과 및 침전과 같은 일반적인 처리공정으로는 제거가 거의 불가능하다. 따라서 흡착, 이온교환, 역삼투, 탈질과 전기투석과 같은 다른 기술이 질산염의 효과적인 제거를 위해 요구된다. 이들 각 기술은 비용, 수질 개선 정도, 잔류물 처리와 전처리 요구와 같은 인자의 비중에 따라 장점과 단점과 가능성을 가지고 있다. 흡착은 가격 효율성, 운전의 용이성과 설계의 간편성으로 가장 보편적으로 사용되는 공정이다. 흡착제의 표면개질은 질산이온 흡착능력을 개선하였다. 역전 전기투석과 역삼투의 질산-선택 멤브레인 공정은 수용액 중의 질산이온 제거에 오랜동안 많은 지역에서 효과적임이 증명되었다. 두 기술은 높은 농도의 폐기물을 생성하고 이것의 신중한 처분이 필요하다.
At high nitrate concentrations, water must be treated to meet regulated concentrations because it results in threat to human health and eutrophication of natural water. However, it is almost impossible to remove nitrate by conventional water treatment methods such as coagulation, filtration and precipitation, due to its high water solubility. Therefore, other technologies including adsorption, ion exchange, reverse osmosis, denitrification, and electrodialysis are required to effectively remove nitrate. Each of these technologies has their own strengths and drawbacks and their feasibility is weighted against factors such as cost, water quality improvement, residuals handling, and pre-treatment requirements. An adsorption technique is the most popular and common process because of its cost effectiveness, ease of operation, and simplicity of design. Surface modifications of adsorbents have been enhanced their adsorption of nitrate. The nitrate-selective membrane process of electrodialysis reversal and reverse osmosis have proven over time and at many locations to be highly effective in removing nitrate contaminating problems in aqueous solutions. Both electrodiaysis and reverse osmosis methods generate highly concentrated wastes and need careful consideration with respect to disposal.
Keywords:Nitrate-nitrogen removal;Adsorption;Electrodialysis reversal;Reverse osmosis;Biological denitrification
  1. Cammargo JA, Alonso A, Environ. Int., 32, 831 (2006)
  2. Fewtrell L, Environ. Health Perspect., 112, 1371 (2004)
  3. Chiu H, Tsai S, Yang C, J. Toxicol. Environ. Health Part A, 70, 1000 (2007)
  4. http://www.epa.gov/ground-water-and-drinking-water/tableregulated-drinking-water-contaminants (accessed Dec. 2016).
  5. http://oneclick.law.go.kr/CSP/CnpClsMain.laf?csmSeq=536&ccfNo=2&cciNo=1&cnpClsNo=1 (accessed Dec. 2016).
  6. WHO, Guidelines for Drinking Water Quality, 4th ed. World Health Organization (2011).
  7. National Health and Medical Research Council, “Australian Drinking Water Guidelines 6” ver. 3.2, Commonwealth of Australia, Canberra (2016).
  8. Ministry of Environment, “White Paper of Environment,” 57-72 (1997).
  9. Ministry of Environment, “Fundamental Plan of Water Environmental Management: Fundamental Plan of Water Quality Protection in the Four Major Rivers (‘06~’15),” 179-190 (2006).
  10. Ministry of Environment, “White Paper of Environment,” 241-306 (2015).
  11. Islam M, Mishra PC, Patel R, J. Environ. Manage., 91, 1883 (2010)
  12. Carroll SB, Salt SD, Ecology for Gardeners, Timber Press, Portland, USA (2004).
  13. Nam YH, An SW, Park JW, J. Korean Soc. Environ. Eng., 33(2), 103 (2011)
  14. Nam YH, An SW, Jung MS, Park JW, J. Korean Soc. Environ. Eng., 34(3), 204 (2012)
  15. Shin JH, Yoo CW, An SW, Park JW, J. Korean Soc. Environ. Eng., 36(2), 75 (2014)
  16. Kapoor A, Viraraghavan T, J. Environ. Eng., 123, 371 (1977)
  17. Bhatnagar A, Sillanpaa M, Chem. Eng. J., 168(2), 493 (2011)
  18. Choi KO, Seo SJ, Ko S, Food Eng. Prog., 18, 36 (2014)
  19. Moreno-Castilla C, Carbon, 42, 83 (2004)
  20. Yang RT, “Adsorbents Fundamentals and Applications,” John Wiley and Sons, New Jersey, USA (2003).
  21. Bhatnagar A, Ji M, Choi YH, Jung W, Lee SH, Kim SJ, Lee G, Suk H, Kim HS, Min B, Kim SH, Jeon BH, Kang JW, Sep. Sci. Technol., 43(4), 886 (2008)
  22. Loganathan P, Vigneswaran S, Kandasamy J, J. Environ. Manage., 131, 363 (2013)
  23. Mizuta K, Matsumoto T, Hatate Y, Nishihara K, Nakanishi T, Bioresour. Technol., 95(3), 255 (2004)
  24. Mishra PC, Patel RK, J. Environ. Manage., 90, 519 (2009)
  25. Demiral H, Gunduzoglu G, Bioresour. Technol., 101(6), 1675 (2010)
  26. Ohe K, Nagae Y, Nakamura S, Baba Y, J. Chem. Eng. Jpn., 36(4), 511 (2003)
  27. Afkhami A, Madrakian T, Karimi Z, J. Hazard. Mater., 144(1-2), 427 (2007)
  28. Khan MA, Ahn YT, Kumar M, Lee W, Min B, Kim G, Cho DW, Park WB, Jeon BH, Sep. Sci. Technol., 46(16), 2575 (2011)
  29. Tofighy MA, Mohammadi T, Chem. Eng. Res. Des., 90(11), 1815 (2012)
  30. Chatterjee S, Woo SH, J. Hazard. Mater., 164(2-3), 1012 (2009)
  31. Chatterjee S, Lee DS, Lee MW, Woo SH, J. Hazard. Mater., 166(1), 508 (2009)
  32. Cengeloglu Y, Tor A, Ersoz M, Arslan G, Sep. Purif. Technol., 51(3), 374 (2006)
  33. Ozturk N, Bektas TE, J. Hazard. Mater., 112(1-2), 155 (2004)
  34. Ozcan A, Sahin M, Ozcan AS, Adsorpt. Sci. Technol., 23, 323 (2005)
  35. Hamoudi S, Saad R, Belkacemi K, Ind. Eng. Chem. Res., 46(25), 8806 (2007)
  36. Arora M, Eddy NK, Mumford KA, Baba Y, Perera JM, Stevens GW, Cold Reg. Sci. Technol., 62, 92 (2010)
  37. Onyango M, Masukume M, Ochieng A, Otieno F, Water SA, 36, 655 (2010)
  38. Xi Y, Mallavarapu M, Naidu R, Appl. Clay Sci., 48, 92 (2010)
  39. Seliem MK, Komarneni S, Byrne T, Cannon FS, Shahien MG, Khalil AA, Abd El-Gaid IM, Sep. Purif. Technol., 110, 181 (2013)
  40. Aghaii MD, Pakizeh M, Ahmadpour A, Sep. Purif. Technol., 113, 24 (2013)
  41. Bhardwaj D, Sharma M, Sharma P, Tomar R, J. Hazard. Mater., 227, 292 (2012)
  42. Yin CY, Aroua MK, Daud WMAW, Sep. Purif. Technol., 52(3), 403 (2007)
  43. Wang S, Ang HM, Tade MO, Chemosphere, 72, 1621 (2008)
  44. Le Cloirec P, Chin. J. Chem. Eng., 20(3), 461 (2012)
  45. Rengel-Mendez JR, Streat M, Water Res., 36, 1244 (2002)
  46. Loganathan P, Vigneswaran S, Kandasamy J, Naidu R, Crit. Rev. Environ. Sci. Technol., 42, 489 (2012)
  47. Namasivayam C, Sangeetha D, Indian J. Chem. Technol., 12(5), 513 (2005)
  48. Natnasivayam C, Sangeetha D, Desalination, 219(1-3), 1 (2008)
  49. Hassan ML, Kassem NF, El-Kader AHA, J. Appl. Polym. Sci., 117(4), 2205 (2010)
  50. Zhang M, Gao B, Yao Y, Xue YW, Inyang M, Chem. Eng. J., 210, 26 (2012)
  51. Kookana RS, Samah AK, van Zweeten L, Knull E, Singh B, Adv. Agron., 112, 103 (2011)
  52. Orlando US, Baes AU, Nishijima W, Okada M, Bioresour. Technol., 83(3), 195 (2002)
  53. Orlando US, Baes AU, Nishijima W, Okada M, Chemosphere, 48, 1041 (2002)
  54. Katal R, Baei MS, Rahmati HT, Esfandian H, J. Ind. Eng. Chem., 18(1), 295 (2012)
  55. Bowman RS, Microporous Mesoporous Mater., 61, 43 (2006)
  56. Haggerty GM, Bownam RS, Environ. Sci. Technol., 28, 452 (1994)
  57. Masukume M, Eskandarpour A, Onyango MS, Ochieng A, Otieno F, Sep. Sci. Technol., 46(7), 1131 (2011)
  58. Islam M, Patel R, J. Hazard. Mater., 190, 120 (2011)
  59. Socias-Viciana MM, Urena-Amate MD, Gonzalez-Pradas E, Garcia-Cortes MJ, Lopez-Teruel C, Clay Clay Min., 56, 2 (2008)
  60. Helfferich FG, Ion Exchange, Dover Publications, New York, USA (1995).
  61. Liang S, Mann MA, Guter GA, Kim PH, Hardan DL, J. Am. Water Works Ass., 91(2), 79 (1999)
  62. Darbi A, Viraraghavan T, Butler R, Corkal D, J. Environ. Sci. Health Part A-Toxic/Hazard. Subst. Environ. Eng., 38(9), 1703 (2003)
  63. Samatya S, Kabay N, Yuksel U, Arda M, Yuksel M, React. Funct. Polym., 66(11), 1206 (2006)
  64. Buelow RW, Jropp KL, Withered J, Symons JM, J. Am. Water Works Ass., 67(9), 528 (1975)
  65. Dore M, Simon PH, Deguin A, Victot J, Water Res., 20(2), 221 (1986)
  66. Kim J, Benjamin MM, Water Res., 38(8), 2053 (2004)
  67. Bergman R, Reverse Osmosis and Nanofiltartion, American Water Works Association, Denver, USA (2007).
  68. Symons JM, Bradley LC, Cleveland TC, The Drinking Water Dictionary, American Water Works Association, McGraw-Hill, New York, USA (2001).
  69. Elyanow D, Presechino J, “Advanced in Nitrate Removal,” GE Water and Process Technologies, Report No. TP-1033EN 0601 (2005).
  70. Soares MIM, Water Air Soil Pollut., 123, 183 (2000)
  71. Shrimali M, Singh KP, Environ. Pollut., 112(3), 351 (2001)
  72. Hiscook KM, Lloyd JM, Lerner DN, Water Res., 25(9), 1099 (1991)
  73. Haugen KS, Semmens MJ, Novak PJ, Water Res., 36(14), 3497 (2002)
  74. Luk GK, Au-Yeung WC, Adv. Environ. Res., 6(4), 441 (2002)
  75. Cheng IF, Muftikian R, Fernando Q, Korte N, Chemosphere, 35(11), 2689 (1997)
  76. Kumar M, Chakraborty S, J. Hazard. Mater., 135(1-3), 112 (2006)
  77. Rautenbach R, Kopp W, Opbergen G, Hellekes R, Desalination, 65, 241 (1987)
  78. Eyal A, Kedem O, Desalination, 38, 101 (1988)