Enhanced Dielectric Properties of Polyimide/BaTiO3 Nanocomposite by Embedding the Polypyrrole@Polyimide Core-Shell Nanoparticles

Hyun Woo Yoon; Changsuk Bok; No Kyun Park; Hyun Min Jung; Yong Seok Kim; Byoung Gak Kim; Dong Hack Suh; Jong Chan Won; Yun Ho Kim

Macromolecular Research, Vol.25, No.3, 290-296, March, 2017

DOI10.1007/s13233-017-5039-3 Export Citation

Enhanced Dielectric Properties of Polyimide/BaTiO3 Nanocomposite by Embedding the Polypyrrole@Polyimide Core-Shell Nanoparticles

Hyun Woo Yoon, Changsuk Bok, No Kyun Park, Hyun Min Jung¹, Yong Seok Kim , Byoung Gak Kim, Dong Hack Suh², Jong Chan Won^†, and Yun Ho Kim^†

Advanced Functional Polymer Research Group, Korea Research Institute of Chemical Technology, Yuseong, Daejeon 34114, Korea
¹Department of Applied Chemistry, Kumoh National Institute of Technology, Gumi, Gyeongbuk 39177, Korea
²Division of Applied Chemical Engineering, Hanyang University, Seongdong-gu, Seoul 04763, Korea

E-mail:,

A three-phase polymer composite with a ferroelectric phase (BaTiO3) and conductive core-shell polypyrrole@polyimide (PPy@PI) nanoparticles embedded in a polyimide (PI) matrix was prepared by using a simple direct mixing and solution casting process. PPy@PI nanoparticles as the conductive filler were synthesized to obtain homogeneous dispersion in the PI matrix. The dependence of the dielectric behavior on the BaTiO3 and PPy@PI contents was studied over a wide frequency range from 10 kHz to 1 MHz. The incorporation of low loading levels of PPy@PI nanoparticles to the PI/BaTiO3 system led to a significant enhancement in the dielectric constant with suppressed loss. The dielectric constant (Dk) of the PI/BaTiO3/PPy@PI (25/75/5) hybrid was 58.53 at 10 kHz, i.e., three times higher than that of the PI/BaTiO3 (25/75) nanocomposite without PPy@PI. The fairly improved dielectric properties were due to the synergistic enhancement of the ferroelectric ceramic filler, BaTiO3, and conductive filler, PPy@PI nanoparticles, as well as due to homogeneous dispersion. Such polymer composites have the potential for use in fabricating embedded capacitors, and specimens with various shapes can be easily obtained owing to the flexibility of the nanocomposite.

Keywords:polymer composite;dielectric property;conducting polymer;core-shell nanoparticle;polyimide

[References]

Barber P, Balasubramanian S, Anguchamy Y, Gong S, Wibowo A, Gao H, Ploehn HJ, Loye HCZ, Materials, 2, 1697 (2009)
Xu W, Ding Y, Jiang S, Ye W, Liao X, Hou H, J. Polym. Sci. A: Polym. Chem., 37, 794 (2016)
Wang J, Qi S, Sun Y, Tian G, Wu D, Func. Mater. Lett., 9, 165000 (2016)
Huang XY, Jiang PK, Adv. Mater., 27(3), 546 (2015)
Lei Q, Dancer CEJ, Grovenor CRM, Grant PS, Compos. Sci. Technol., 129, 198 (2016)
Wu C, Huang X, Wu X, Yu J, Xie L, Jiang P, Compos. Sci. Technol., 72, 521 (2012)
Zhang X, Shen Y, Zhang QH, Gu L, Hu YH, Du JW, Lin YH, Nan CW, Adv. Mater., 27(5), 819 (2015)
Xu N, Hu L, Zhang Q, Xiao X, Yang H, Yu E, ACS Appl. Mater. Interfaces, 7, 27373 (2015)
Yang K, Huang X, He J, Jiang P, Adv. Mater. Inter., 2, 150036 (2015)
Huo X, Li W, Zhu J, Li L, Li Y, Luo L, Zhu Y, J. Phys. Chem. C, 119, 25786 (2015)
Han QLK, Gadinski MR, Zhang GZ, Wang Q, Adv. Mater., 26(36), 6244 (2014)
Cui X, Zhu G, Liu W, Polym. Korea, 40(4), 587 (2016)
Wan YJ, Yang WH, Yu SH, Sun R, Wong CP, Liao WH, Compos. Sci. Technol., 122, 27 (2016)
Guo Q, Xue Q, Sun J, Dong M, Xia F, Zhang Z, Nanoscale, 7, 3660 (2015)
Ameli A, Nofar M, Park CB, Potschke P, Rizvi G, Carbon, 71, 206 (2014)
Xu W, Ding Y, Jiang S, Chen L, Liao X, Hou H, Mater. Lett., 135, 158 (2014)
Dang ZM, Zheng MS, Zha JW, Small, 12, 1688 (2016)
Kim JY, Lee WH, Suk JW, Potts JR, Chou H, Kholmanov IN, Piner RD, Lee J, Akinwande D, Ruoff RS, Adv. Mater., 25(16), 2308 (2013)
Thomassin JM, Trifkovic M, Alkarmo W, Detrembleur C, Jerome C, Macosko C, Macromolecules, 47(6), 2149 (2014)
Liu J, Tian G, Qi S, Wu Z, Wu D, Mater. Lett., 124, 117 (2014)
Li C, Yu S, Luo S, Yang W, Ge Z, Huang H, Sun R, Wong CP, RSC Adv., 6, 36450 (2016)
Zhang L, Bass P, Cheng ZY, Appl. Phys. Lett., 105, 42905 (2014)
Deng H, Lin L, Ji M, Zhang S, Yang M, Fu Q, Prog. Polym. Sci, 39, 627 (2014)
Inui T, Koga H, Nogi M, Komoda N, Suganuma K, Adv. Mater., 27(6), 1112 (2015)
da Silva AB, Arjmand M, Sundararaj U, Bretas RES, Polymer, 55(1), 226 (2014)
Yang TI, Chuang CY, Yang SC, Kempel LC, Kofinas P, Adv. Eng. Mater., 18, 121 (2016)
Park JY, Oh KO, Won JC, Han H, Jung HM, Kim YS, J. Mater. Chem., 22, 16005 (2012)
Kobayashi D, Endo Y, Sakamoto T, Takahashi T, Matsumoto H, Kuroda C, Otake K, Shono A, Macromol. Symp., 324, 55 (2013)
Kim BG, Kim YS, Kim YH, Kim H, Hong YJ, Jung HM, Won JC, Compos. Sci. Technol., 129, 153 (2016)
Zhang X, Bai RB, Langmuir, 19(26), 10703 (2003)
Park SK, Farris RJ, Polymer, 42(26), 10087 (2001)
Ahmad Z, Mark JE, Chem. Mater., 13, 3320 (2001)
Arlt G, Hennings D, de With G, J. Appl. Phys., 58, 1619 (1985)
Li YC, Tjong SC, Li RKY, Express Polym. Lett., 5, 526 (2011)
Qi L, Lee BI, Chen SH, Samuels WD, Exarhos GJ, Adv. Mater., 17(14), 1777 (2005)

[Referenced By]

[Related Articles]

[1] Barber P, Balasubramanian S, Anguchamy Y, Gong S, Wibowo A, Gao H, Ploehn HJ, Loye HCZ, Materials, 2, 1697 (2009)

[2] Xu W, Ding Y, Jiang S, Ye W, Liao X, Hou H, J. Polym. Sci. A: Polym. Chem., 37, 794 (2016)

[3] Wang J, Qi S, Sun Y, Tian G, Wu D, Func. Mater. Lett., 9, 165000 (2016)

[4] Huang XY, Jiang PK, Adv. Mater., 27(3), 546 (2015)

[5] Lei Q, Dancer CEJ, Grovenor CRM, Grant PS, Compos. Sci. Technol., 129, 198 (2016)

[6] Wu C, Huang X, Wu X, Yu J, Xie L, Jiang P, Compos. Sci. Technol., 72, 521 (2012)

[7] Zhang X, Shen Y, Zhang QH, Gu L, Hu YH, Du JW, Lin YH, Nan CW, Adv. Mater., 27(5), 819 (2015)

[8] Xu N, Hu L, Zhang Q, Xiao X, Yang H, Yu E, ACS Appl. Mater. Interfaces, 7, 27373 (2015)

[9] Yang K, Huang X, He J, Jiang P, Adv. Mater. Inter., 2, 150036 (2015)

[10] Huo X, Li W, Zhu J, Li L, Li Y, Luo L, Zhu Y, J. Phys. Chem. C, 119, 25786 (2015)

[11] Han QLK, Gadinski MR, Zhang GZ, Wang Q, Adv. Mater., 26(36), 6244 (2014)

[12] Cui X, Zhu G, Liu W, Polym. Korea, 40(4), 587 (2016)

[13] Wan YJ, Yang WH, Yu SH, Sun R, Wong CP, Liao WH, Compos. Sci. Technol., 122, 27 (2016)

[14] Guo Q, Xue Q, Sun J, Dong M, Xia F, Zhang Z, Nanoscale, 7, 3660 (2015)

[15] Ameli A, Nofar M, Park CB, Potschke P, Rizvi G, Carbon, 71, 206 (2014)

[16] Xu W, Ding Y, Jiang S, Chen L, Liao X, Hou H, Mater. Lett., 135, 158 (2014)

[17] Dang ZM, Zheng MS, Zha JW, Small, 12, 1688 (2016)

[18] Kim JY, Lee WH, Suk JW, Potts JR, Chou H, Kholmanov IN, Piner RD, Lee J, Akinwande D, Ruoff RS, Adv. Mater., 25(16), 2308 (2013)

[19] Thomassin JM, Trifkovic M, Alkarmo W, Detrembleur C, Jerome C, Macosko C, Macromolecules, 47(6), 2149 (2014)

[20] Liu J, Tian G, Qi S, Wu Z, Wu D, Mater. Lett., 124, 117 (2014)

[21] Li C, Yu S, Luo S, Yang W, Ge Z, Huang H, Sun R, Wong CP, RSC Adv., 6, 36450 (2016)

[22] Zhang L, Bass P, Cheng ZY, Appl. Phys. Lett., 105, 42905 (2014)

[23] Deng H, Lin L, Ji M, Zhang S, Yang M, Fu Q, Prog. Polym. Sci, 39, 627 (2014)

[24] Inui T, Koga H, Nogi M, Komoda N, Suganuma K, Adv. Mater., 27(6), 1112 (2015)

[25] da Silva AB, Arjmand M, Sundararaj U, Bretas RES, Polymer, 55(1), 226 (2014)

[26] Yang TI, Chuang CY, Yang SC, Kempel LC, Kofinas P, Adv. Eng. Mater., 18, 121 (2016)

[27] Park JY, Oh KO, Won JC, Han H, Jung HM, Kim YS, J. Mater. Chem., 22, 16005 (2012)

[28] Kobayashi D, Endo Y, Sakamoto T, Takahashi T, Matsumoto H, Kuroda C, Otake K, Shono A, Macromol. Symp., 324, 55 (2013)

[29] Kim BG, Kim YS, Kim YH, Kim H, Hong YJ, Jung HM, Won JC, Compos. Sci. Technol., 129, 153 (2016)

[30] Zhang X, Bai RB, Langmuir, 19(26), 10703 (2003)

[31] Park SK, Farris RJ, Polymer, 42(26), 10087 (2001)

[32] Ahmad Z, Mark JE, Chem. Mater., 13, 3320 (2001)

[33] Arlt G, Hennings D, de With G, J. Appl. Phys., 58, 1619 (1985)

[34] Li YC, Tjong SC, Li RKY, Express Polym. Lett., 5, 526 (2011)

[35] Qi L, Lee BI, Chen SH, Samuels WD, Exarhos GJ, Adv. Mater., 17(14), 1777 (2005)