화학공학소재연구정보센터
Korean Journal of Materials Research, Vol.27, No.3, 127-131, March, 2017
부피법을 이용한 저온 등량 수소 흡착열 측정법 개선
Improvement of Accuracy for Determination of Isosteric Heat of Hydrogen Adsorption
E-mail:
Isosteric heat of hydrogen adsorption is one of the most important parameters required to describe solid-state hydrogen storage systems. Typically, it is calculated from adsorption isotherms measured at 77K (liquid N2) and 87K (liquid Ar). This simple calculation, however, results in a high degree of uncertainty due to the small temperature range. Therefore, the original Sievert type setup is upgraded using a heating and cooling device to regulate the wide sample temperature. This upgraded setup allows a wide temperature range for isotherms (77K ~ 117K) providing a minimized uncertainty (error) of measurement for adsorption enthalpy calculation and yielding reliable results. To this end, we measure the isosteric heats of hydrogen adsorption of two prototypical samples: activated carbon and metal-organic frameworks (e.g. MIL-53), and compared the small temperature range (77~87K) to the wide one (77K ~ 117K).
  1. Broom DP, Int. J. Hydrog. Energy, 32(18), 4871 (2007)
  2. Zlotea C, Moretto P, Steriotis T, Int. J. Hydrog. Energy, 34(7), 3044 (2009)
  3. Oh H, Trans. Korean Hydrogen New Energy Soc., 27, 349 (2016)
  4. Broom DP, Hirscher M, Energy Environ. Sci., 9, 3368 (2016)
  5. Rouquerol F, Rouquerol J, Sing K, Adsorption by Powders and Porous Solids, Academic Press, (1999).