Bi 과잉에 따른 BiFeO3-BaTiO3 세라믹스의 압전 및 유전특성

이재홍; 이명환; 송태권; 김원정; 성연수; 김명호; Jae Hong Lee; Myang Hwan Lee; Tae Kwon Song; Won-Jeong Kim; Yeon Soo Sung; Myong-Ho Kim

Korean Journal of Materials Research, Vol.27, No.3, 144-148, March, 2017

DOI10.3740/MRSK.2017.27.3.144 Export Citation

Bi 과잉에 따른 BiFeO3-BaTiO3 세라믹스의 압전 및 유전특성

Effect of Bismuth Excess on Piezoelectric and Dielectric Properties of BiFeO3-BaTiO3 Ceramics

이재홍, 이명환, 송태권, 김원정¹, 성연수^{2, †}, 김명호^†

창원대학교 신소재공학부
¹창원대학교 물리학과
²포항공과대학교 신소재공학과

Jae Hong Lee, Myang Hwan Lee, Tae Kwon Song, Won-Jeong Kim¹, Yeon Soo Sung^{2, †}, and Myong-Ho Kim^†

School of Advanced Materials and Engineering, Changwon National University, Changwon 51140, Republic of Korea
¹Department of Physics, Changwon National University, Changwon 51140, Republic of Korea
²Department of Materials and Engineering, Technology (POSTECH), Pohang 37673, Republic of Korea

E-mail:,

The effects of an excess of Bi on the piezoelectric and dielectric properties of 0.60Bi1+xFeO3-0.40BaTiO3 (x = 0, 0.01, 0.03, 0.05, 0.07) were investigated. The ceramics were processed through a conventional solid state reaction method and then quenched after sintering at different temperatures in the range of 980~1070 °C. A single perovskite structure without any secondary phase was confirmed for all compositions and temperatures. It was found that excess Bi reduced the sintering temperatures, acted as a sintering aid and enhanced the properties in combination with quenching. Curie temperature (TC) was found to slightly increase due to the presence of excess Bi; electrical properties were also improved by quenching. At x = 0.03 and 1030 °C, remnant polarization (2Pr) was as high as 45.4 μC/cm2 and strain at 40 kV/cm was up to 0.176 %.

Keywords:BiFeO3-BaTiO3 system;Bi excess;strain;curie temperature;lead-free

[References]

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Malik RA, Hussain A, Zaman A, Maqbool A, Rahman JU, Song TK, Kim WJ, Kim MH, RSC Adv., 5, 96953 (2015)
Takenaka T, Nagata H, J. European Ceram. Soc., 25, 2693 (2005)
Krainik NN, Khuchua NP, Zhdanova VV, Evseev VA, Sov. Phys. Solid State, 8, 654 (1966)
Leontsev SO, Eitel RE, J. Am. Ceram. Soc., 92(12), 2957 (2009)
Cheon CI, Choi JH, Kim JS, Zang J, Fromling T, Rodel J, Jo W, J. Appl. Phys., 119, 154101 (2016)
Pradhan AK, Zhang K, Hunter D, Dadson JB, Loutts GB, AAPG Bull., 97, 093903 (2005)
Lin YH, Jiang Q, Wang Y, Nan CW, Chen L, Yu J, Appl. Phys. Lett., 90, 172507 (2007)
Cheng ZX, Li AH, Wang XL, Dou SX, Ozawa K, Kimura H, Zhang SJ, Shrout TR, J. Appl. Phys., 103, 07E507 (2008)
Suresh P, Srinath S, J. Alloy. Compd., 554, 271 (2013)
Nalwa KS, Garg A, J. Appl. Phys., 103, 044101 (2008)
Karimi S, Reaney IM, Han Y, Pokorny J, Sterianou I, J. Mater. Sci., 44(19), 5102 (2009)
Lee MH, Kim DJ, Park JS, Kim SW, Song TK, Kim MH, Kim WJ, Do D, Jeong IK, Adv. Mater., 27(43), 6976 (2015)
Zhou C, Yang H, Zhou Q, Cen Z, Li W, Yuan C, Wang H, Ceram. Int., 39, 4307 (2013)
Ma ZZ, Tian ZM, Li JQ, Wang CH, Huo SX, Duan HN, Yuan SL, Solid State Sci., 13, 2196 (2011)
Wang QQ, Wang Z, Liu XQ, Chen XM, J. Am. Ceram. Soc., 95(2), 670 (2012)
Randall CA, Newnham RE, Cross LE, “History of the First Ferroelectric Oxide, BaTiO3”, Materials Research Institute, The Pennsylvania State University, USA, (2004).
Chen J, Cheng J, J. Alloy. Compd., 589, 115 (2014)
Zhou C, Yang H, Zhou Q, Chen G, Li W, Wang H, J. Mater. Sci., 24, 1685 (2013)
Du HL, Liu DJ, Tang FS, Zhu DM, Zhou WC, J. Am. Ceram. Soc., 90(9), 2824 (2007)
Fan Q, Zhou C, Zeng W, Cao L, Yuan C, Rao G, Li X, J. Electroanal. Chem., 36, 1 (2016)

[Referenced By]

[1] Jaffe B, Roth RS, Marzullo S, J. Appl. Phys., 25, 809 (1954)

[2] Malik RA, Hussain A, Zaman A, Maqbool A, Rahman JU, Song TK, Kim WJ, Kim MH, RSC Adv., 5, 96953 (2015)

[3] Takenaka T, Nagata H, J. European Ceram. Soc., 25, 2693 (2005)

[4] Krainik NN, Khuchua NP, Zhdanova VV, Evseev VA, Sov. Phys. Solid State, 8, 654 (1966)

[5] Leontsev SO, Eitel RE, J. Am. Ceram. Soc., 92(12), 2957 (2009)

[6] Cheon CI, Choi JH, Kim JS, Zang J, Fromling T, Rodel J, Jo W, J. Appl. Phys., 119, 154101 (2016)

[7] Pradhan AK, Zhang K, Hunter D, Dadson JB, Loutts GB, AAPG Bull., 97, 093903 (2005)

[8] Lin YH, Jiang Q, Wang Y, Nan CW, Chen L, Yu J, Appl. Phys. Lett., 90, 172507 (2007)

[9] Cheng ZX, Li AH, Wang XL, Dou SX, Ozawa K, Kimura H, Zhang SJ, Shrout TR, J. Appl. Phys., 103, 07E507 (2008)

[10] Suresh P, Srinath S, J. Alloy. Compd., 554, 271 (2013)

[11] Nalwa KS, Garg A, J. Appl. Phys., 103, 044101 (2008)

[12] Karimi S, Reaney IM, Han Y, Pokorny J, Sterianou I, J. Mater. Sci., 44(19), 5102 (2009)

[13] Lee MH, Kim DJ, Park JS, Kim SW, Song TK, Kim MH, Kim WJ, Do D, Jeong IK, Adv. Mater., 27(43), 6976 (2015)

[14] Zhou C, Yang H, Zhou Q, Cen Z, Li W, Yuan C, Wang H, Ceram. Int., 39, 4307 (2013)

[15] Ma ZZ, Tian ZM, Li JQ, Wang CH, Huo SX, Duan HN, Yuan SL, Solid State Sci., 13, 2196 (2011)

[16] Wang QQ, Wang Z, Liu XQ, Chen XM, J. Am. Ceram. Soc., 95(2), 670 (2012)

[17] Randall CA, Newnham RE, Cross LE, “History of the First Ferroelectric Oxide, BaTiO3”, Materials Research Institute, The Pennsylvania State University, USA, (2004).

[18] Chen J, Cheng J, J. Alloy. Compd., 589, 115 (2014)

[19] Zhou C, Yang H, Zhou Q, Chen G, Li W, Wang H, J. Mater. Sci., 24, 1685 (2013)

[20] Du HL, Liu DJ, Tang FS, Zhu DM, Zhou WC, J. Am. Ceram. Soc., 90(9), 2824 (2007)

[21] Fan Q, Zhou C, Zeng W, Cao L, Yuan C, Rao G, Li X, J. Electroanal. Chem., 36, 1 (2016)