Journal of Industrial and Engineering Chemistry, Vol.49, 152-157, May, 2017
Post combustion capture and conversion of carbon dioxide using histidine derived ionic liquid at ambient conditions
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The present work describes a simple, highly efficient and cost effective approach for efficient capturing of CO2 and its conversion into high value product by using amino acid derived task specific ionic liquids (AAIL). Among the three different kinds of amino acid (histidine, aspartic acid and glutamic acid) derived ionic liquids studied, histidine derived amino acid ionic liquid was found to be an efficient capturing medium for CO2 and its conversion to corresponding cyclic carbonates by reaction with epoxides under ambient reaction conditions at atmospheric pressure using dimethylcarbonate as reaction medium. The salient features of the developed methodology are the use of biocompatible amino acid derived ionic liquid, efficient capturing and conversion of carbon dioxide, metal free system, excellent product yields and atmospheric pressure condition.
Keywords:Ionic liquid;CO2 capture and utilization;Cyclic carbonate;Amino acid ionic liquid;Green chemistry
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