화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.49, 176-188, May, 2017
DOI10.1016/j.jiec.2017.01.025  Export Citation
Pyrimidine derivatives as novel acidizing corrosion inhibitors for N80 steel useful for petroleum industry: A combined experimental and theoretical approach
Jiyaul Haque, K.R. Ansari, Vandana Srivastava, M.A. Quraishi†, and I.B. Obot1
  • Department of Chemistry, Indian Institute of Technology (Banaras Hindu University), Varanasi 221005, India
  • 1Centre of Research Excellence in Corrosion, Research Institute, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia
E-mail:
The corrosion inhibition performance of two pyrimidine derivatives namely 5-styryl-2,7-dithioxo- 2,3,5,6,7,8-hexahydropyrimido[4,5-d] pyrimidin-4(1H) one (PP-1) and 5-(2-hydroxyphenyl)-2,7-dithioxo-2,3,5,6,7,8-hexahydropyrimido[4,5-d]-pyrimidin-4(1H) one (PP-2) on N80 steel corrosion in 15% HCl has been studied using gravimetric method, electrochemical impedance spectroscopy (EIS), potentiodynamic polarization, atomic force microscopy (AFM), scanning electron microscopy (SEM), DFT, molecular electrostatic potential and Monte Carlo simulation. The corrosion inhibition efficiencies at optimum concentration (250 mg/L) are 89.1% (PP-1) and 73.1% (PP-2) respectively at 308 K. The corrosion inhibition efficiency increases with increase in concentration and decreases with temperature. PPs obeyed Langmuir adsorption isotherm. AFM and SEM analyses supported formation of protective film on N80 steel in presence of inhibitors. DFT and Monte Carlo simulation calculations supported experimental results.
Keywords:N80 steel;SEM;AFM;Pyrimidine derivatives;Quantum chemical calculation
  1. Saji VS, Recent Pat. Corros. Sci., 2, 6 (2010)
  2. Acidizing-Treatment in Oil Gas Operators, American Petroleum Institute, 2014 DM2014-113.
  3. Crowe C, Masmonteil J, Thomas R, Oilfield Rev., 4, 22 (1992)
  4. Ansari KR, Quraishi MA, Singh A, Measurement, 76, 136 (2015)
  5. Badr GE, Corrosion Sci., 51, 2529 (2009)
  6. Obot IB, Madhankumar A, Mater. Chem. Phys., 177, 266 (2016)
  7. Yadav M, Kumar S, Sharma U, Yadav PN, J. Mater. Environ. Sci., 4, 691 (2013)
  8. Ajmal M, Mideen AS, Quraishi MA, Corrosion Sci., 36, 79 (1994)
  9. Williams DA, Holifield PK, Looney JR, McDougall LA, Method of inhibiting corrosion in acidizing wells, in: US Patent 5,200,096, Exxon Chemicals Patents, Inc., Linden, N.J., 1993.
  10. Ozcan M, Dehri I, Erbil M, Appl. Surf. Sci., 236(1-4), 155 (2004)
  11. Neemla KD, Jayaraman A, Saxena RC, Agrawal AK, Krishna R, Bull. Electrochem., 5, 250 (1989)
  12. Frenier WW, Growcock FB, Lopp VR, Corrosion, 44, 590 (1988)
  13. Ansari KR, Sudheer, Singh A, Quraishi MA, J. Dispers. Sci. Technol., 36, 908 (2015)
  14. Hejazi S, Mohajernia S, Moayed MH, Davoodi A, Rahimizadeh M, Momeni M, Eslami A, Shiri A, Kosari A, J. Ind. Eng. Chem., 25, 112 (2015)
  15. Caliskan N, Akbas E, Mater. Chem. Phys., 126(3), 983 (2011)
  16. Li X, Xie X, Deng S, Du G, Corrosion Sci., 87, 27 (2014)
  17. Aly HM, Saleh NM, Int. J Adv. Res., 2, 694 (2014)
  18. Ansari KR, Quraishi MA, Physica E, 69, 322 (2015)
  19. Awad MK, Mustafa KR, Elnga MMA, J. Mol. Struct. THEOCHEM, 959, 66 (2010)
  20. Paulin L, The Nature of the Chemical Bond, Coruell University Press, Ithaca, New York, 1960.
  21. Martinez S, Mater. Chem. Phys., 77(1), 97 (2003)
  22. Frisch MJ, et al., Gaussian 03, Revision E.01, Gaussian Inc., Wallingford, CT, 2007.
  23. Singh A, Lin YH, Obot IB, Ebenso EE, Ansari KR, Quraishi MA, Appl. Surf. Sci., 356, 341 (2015)
  24. Fragoza-Mar L, Olivares-Xometl O, Dominguez-Aguilar MA, Flores EA, Arellanes-Lozada P, Jimenez-Cruz F, Corrosion Sci., 61, 171 (2012)
  25. Ansari KR, Quraishi MA, Singh A, Corrosion Sci., 95, 62 (2015)
  26. Ansari KR, Quraishi MA, Singh A, Corrosion Sci., 79, 5 (2014)
  27. Yadav M, Kumar S, Sharma D, Anti Corros. Methods Mater., 61, 129 (2014)
  28. Shukla SK, Ebenso EE, Int. J. Electrochem. Sci., 6, 3277 (2011)
  29. Rosenfeld LL, Corrosion Inhibitors, McGraw-Hill, New York, 1981.
  30. Umoren SA, Li Y, Wang FH, Corrosion Sci., 52, 1777 (2010)
  31. Bentiss F, Lebrini M, Lagrenee M, Corrosion Sci., 47, 2915 (2005)
  32. Ansari KR, Quraishi MA, Singh A, Ramkumar S, Obot IB, RSC Adv., 6, 24130 (2016)
  33. Labjar N, Lebrini M, Bentiss F, Chihib NE, El Hajjaji S, Jama C, Mater. Chem. Phys., 119(1-2), 330 (2010)
  34. Yadav M, Kumar S, Sinha RR, Bahadur I, Ebenso EE, J. Mol. Liq., 211, 135 (2015)
  35. Singh A, Lin YH, Ansari KR, Quraishi MA, Ebenso EE, Chen SS, Liu WY, Appl. Surf. Sci., 359, 331 (2015)
  36. Donahue FM, Akiyama A, Nobe K, J. Electrochem. Soc., 114, 1006 (1967)
  37. Donahue FM, Akiyama A, Nobe K, J. Electrochem. Soc., 114, 1012 (1967)
  38. Smialowaska S, Hydrogen Embrittlement of Low Strength Steel. ARPA Handbook on Stess Corrosion Craking, (1977) p. 172.
  39. Vengatesh G, Karthik G, Sundaravadivelu M, Egypt. J. Pet. (2016), doi:http:// dx.doi.org/10.1016/j.ejpe.2016.10.011.
  40. Ansari KR, Quraishi MA, J. Ind. Eng. Chem., 20(5), 2819 (2014)
  41. Obi-Egbedi NO, Obot IB, Corrosion Sci., 53, 263 (2011)
  42. Gece G, Corrosion Sci., 50, 2981 (2008)
  43. Hu J, Wang Y, Yu L, Zou Y, Wang Y, Int. J. Corros. (2015), doi:http://dx.doi.org/ 10.1155/2015/548031.
  44. Yadav M, Sharma D, Kumar S, Korean J. Chem. Eng., 32(5), 993 (2015)
  45. Tian H, Li W, Cao K, Hou B, Corrosion Sci., 73, 281 (2013)
  46. Hegazy MA, Badawi AM, Abd El Rehim SS, Kamel WM, Corrosion Sci., 69, 110 (2013)
  47. Kovacevic N, Kokalj A, Corrosion Sci., 73, 7 (2013)
  48. Deng S, Li X, Xie X, Corrosion Sci., 80, 276 (2014)
  49. Abdullach M, Corrosion Sci., 44, 717 (2002)
  50. El Adnani Z, Mcharfi M, Sfaira M, Benzakour M, Benjelloun AT, EbnTouhami M, Corrosion Sci., 68, 223 (2013)
  51. Cao Z, Tang Y, Cang H, Xu J, Lu G, Jing W, Corrosion Sci., 83, 292 (2014)
  52. Obot IB, Macdonald DD, Gasem ZM, Corrosion Sci., 99, 1 (2015)
  53. Yadav M, Sinha RR, Sarkar TK, Bahadur I, Ebenso EE, J. Mol. Liq., 212, 686 (2015)
  54. Garza AJ, Scuseria GE, Khan SB, Asiri AM, Chem. Phys. Lett., 575, 122 (2013)
  55. El Belghiti M, Karzazia Y, Dafali A, Hammouti B, Bentiss F, Obotd IB, Bahadure I, Ebenso EE, J. Mol. Liq., 218, 281 (2016)