A Sr0.85Ce0.15FeO3-delta perovskite-type mixed oxide was prepared by solution combustion synthesis from citric acid and carefully characterized for the structure by X-ray diffraction coupled with Rietveld analysis, for the microstructure/morphology by HRTEM and SEM, for texture by N-2 uptake at low temperature, for surface charge by zeta potential measurements and for reactive species by Electron Paramagnetic Resonance (EPR). Photocatalytic activity was tested in the presence of simulated solar light towards Orange II and Rhodamine B as model pollutants. Despite this compound is known as photocatalyst, a good reactivity was evidenced in the 55-80 degrees C temperature range without light irradiation, indicating that it can work as well in the dark after thermal-activation. Therefore, experimental data obtained in this work suggest to carefully reconsidering the role of this mixed oxide as photocatalyst. EPR spin-trapping tests allowed to deepen the aspects related to reactive species generated by Sr0.85Ce0.15FeO3-delta, revealing that the temperature increase promotes hydroxyl radicals and singlet oxygen production. Furthermore, an interesting selectivity towards the degradation of different dyes was found. (C) 2017 Elsevier B.V. All rights reserved.