A Mixed-Cluster Approach for Building a Highly Porous Cobalt(II) Isonicotinic Acid Framework: Gas Sorption Properties and Computational Analyses

Chen DM; Zhang NN; Liu CS; Jiang ZH; Wang XD; Du M

Inorganic Chemistry, Vol.56, No.5, 2379-2382, 2017

DOI10.1021/acs.inorgchem.6b03170 Export Citation

A Mixed-Cluster Approach for Building a Highly Porous Cobalt(II) Isonicotinic Acid Framework: Gas Sorption Properties and Computational Analyses

Chen DM, Zhang NN, Liu CS, Jiang ZH, Wang XD, Du M

A unique channel-type metal-organic framework (MOF) built up from mixed square-planar Co-4(mu(2)-OH)(4)(mu(4)-OH) and cuboidal Co-4(mu(3)-OH)(4) clusters with an isonicotinic acid ligand has been successfully fabricated that demonstrates the highest specific surface area and high H-2 uptake capacities among all of the cobalt(II) isonicotinic acid frameworks reported so far.