The aim of the current study was to examine the effects of group 13 metals on Cp2TiCl2 reduction in the presence of 2-methoxy-ethanol (MeOEtOH) or ethanol (EtOH) and the compositions of the resulting products. Direct reaction of Cp2TiCl2 and M [Al, Al (Fe contaminated), Ga, In] in toluene/alcohol for 2 h gave a new family of uncommon homo-and heterometallic compounds: [Cp2Ti2Al(mu,eta(2)-OEt-OMe)(4)Cl-2][Ti-2(mu,eta(2)-OEtOMe)(3)(eta(2)-OEtOMe)(2)Cl-4] (1), [CE2Ti2Al(mu,eta 2-OEtOMe)(4)Cl-2] Cl (2), [CP2Ti2Al(mu,eta(2)-OEtOMe)(4)Cl-2] [Cp2Ti(eta(2)-HOEt-OMe)] [FeCl4] (3), [Cp2Ti(eta(2)-HOEtOMe)][Ga2Cl6](0.25)[Cl](0.5) (4), [Cp3Ti2(mu-OEt)(2)(OEt)][GaCl4] (5), [CpTi(mu,eta(2)-OEtOMe)Cl](2) (6), and [Cp3Ti2(mu,eta(2)-OEtOMe)(mu-OEtOMe)Cl] (7). The reaction with indium for 48 h resulted in isolation of [TiIn2(mu,eta(2)-OEtOMe)(4)(OEtOMe)(2)Cl-4] (8), [In-2(mu-OEtOMe)(2)(HOEtOMe)(4)Cl-4](2) (9), and [Ti(OEtOMe)(4)] (10). The complexes were characterized using elemental analysis, IR and NMR spectroscopies, and, for 1-9, single-crystal X-ray diffraction. The use of metallic gallium and indium to reduce Cp2TiCl2 opens up a previously unexplored path that may provide access to novel and unique compounds.